Water-Based Ink Set for Stable Color Performance

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Solution Overview

Problem

Water-based ink sets for ink-jet recording face challenges in maintaining color stability and durability against light, heat, and ozone, particularly in high humidity environments, where specific dyes used can diffuse easily, affecting the color tone of secondary colors created by mixing different inks.

Innovation Solution

A water-based ink set comprising at least two inks, one containing a dye represented by a specific formula and another with a cationic polymer, which suppresses color change in high humidity environments by interacting with the ink-receiving layer of the recording medium.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a specific dye is used to achieve satisfactory hue and durability against light, heat, and ozone, then color fastness is improved, but diffusion control in high humidity environments deteriorates

Engineering Contradiction:
Improvecolor fastnessVSAvoidcolor tone stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent introduces a specific surfactant as an intermediary substance between the specific dye and the recording medium. This surfactant modifies the interaction interface, allowing the dye to maintain its durability properties while reducing excessive diffusion in high humidity environments. The surfactant acts as a mediator that controls the wetting and diffusion behavior of the dye without compromising its inherent fastness properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical composition parameters of the ink by incorporating a specific surfactant with defined molecular structure and concentration ranges. This parameter change affects the surface tension and wetting properties of the ink, thereby controlling the diffusion behavior of the specific dye on the recording medium while preserving its color fastness characteristics.

Inventive Principle:
Principle #35Parameter changes

2Adaptability or versatility

If humidity increases in the environment, then diffusion of specific dye into recording medium increases, but color tone accuracy deteriorates

Engineering Contradiction:
Improveenvironmental adaptabilityVSAvoidcolor tone accuracy
Core Design Contradiction:
Adaptability or versatilityVSManufacturing precision

Solution Approach 1:

The surfactant serves as an intermediary that buffers the effect of environmental humidity on dye diffusion. By modifying the ink's surface properties, the surfactant creates a controlled diffusion pathway that is less sensitive to humidity variations, thereby maintaining color tone accuracy across different environmental conditions.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The surfactant is incorporated into the ink formulation in advance to preemptively counteract the harmful effect of humidity-induced diffusion. This preliminary anti-action prevents the dye from diffusing excessively when exposed to high humidity, thereby preserving color tone accuracy before the diffusion problem can manifest.

Inventive Principle:
Principle #9Preliminary anti-action

3Stability of the object's composition

If cationic polymer is added to suppress color change in high humidity, then color stability is improved, but jetting stability may deteriorate

Engineering Contradiction:
Improvecolor stabilityVSAvoidjetting stability
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent carefully controls the concentration parameter of the cationic polymer within a specific range (0.01-5% by weight). This parameter optimization ensures that the polymer provides sufficient color stability in high humidity environments while maintaining jetting stability. The precise concentration control balances the competing requirements of color fixation and ink flow properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink formulation by combining the specific dye, surfactant, and cationic polymer in defined proportions. This composite material approach allows the components to work synergistically, where the surfactant and polymer together provide color stability without the polymer alone causing jetting issues. The composite formulation balances multiple functional requirements.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink set provides stable and durable color performance against light, heat, and ozone, with suppressed color change in high humidity conditions, ensuring excellent jetting stability and optical density.

Implementation Method 1

another with a cationic polymer, which suppresses color change in high humidity environments by interacting with the ink-receiving layer of the recording medium

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS8864297B2Water-based ink set for ink-jet recording, ink-jet recording method and ink-jet recording apparatus
Publication Date: 2014.10.21 BROTHER KOGYO KK
  • US8864297B2 patent drawing
  • US8864297B2 patent drawing
  • US8864297B2 patent drawing

AI summary

A water-based ink set for ink-jet recording includes two or more kinds of water-based inks; wherein at least one water-based ink among the two or more kinds of water-based inks contains a dye represented by a general formula (1) and at least one water-based inks contains 0.5% by weight to 4% by weight a cationic polymer; and in the general formula (1): n1 is 1 or 2, each of three Ms is sodium or ammonium and the three Ms may be same or different from one another, and R0 represents a monoalkylamino group substituted by a carboxyl group and having a number of carbon atoms of 1 to 8.