Water-Based Ink Surfactant Stabilization

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Solution Overview

Problem

Existing water-based inks for ink-jet recording face challenges in stabilizing the dispersion of water-insoluble liquids, which affects their drying properties and overall performance.

Innovation Solution

A water-based ink formulation that includes a water-soluble colorant, water, a water-insoluble liquid, a nonionic surfactant, and an ionic surfactant with the same polarity as the colorant, which stabilizes the dispersion of the water-insoluble liquid, enhancing its drying properties and functionality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If a water-insoluble liquid is added to water-based ink to improve drying property, then drying property is improved, but the water-insoluble liquid cannot be stably dispersed in the water-based ink

Engineering Contradiction:
Improvedrying propertyVSAvoiddispersion stability
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

A surfactant is introduced as an intermediary substance to mediate between the water-insoluble liquid and water-based ink. The surfactant contains both hydrophilic and hydrophobic groups, allowing it to stabilize the interface between water and oil phases, enabling stable dispersion of water-insoluble liquid in water-based ink while maintaining improved drying properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The ink formulation uses a composite approach by combining water-soluble components (water, colorant) with water-insoluble components (liquid paraffin, etc.) through the use of surfactant, creating a stable emulsion system that exhibits properties of both phases - the drying enhancement from water-insoluble liquid and the stability from water-based continuity.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If a water-insoluble liquid is added to water-based ink to provide new functions, then functionality is enhanced, but the dispersed state cannot be maintained for a long period of time

Engineering Contradiction:
ImprovefunctionalityVSAvoidstorage stability
Core Design Contradiction:
Adaptability or versatilityVSDuration of action of stationary object

Solution Approach 1:

The surfactant acts as a long-term stabilizing intermediary that prevents phase separation during storage. It forms a protective interface around water-insoluble liquid droplets, maintaining the emulsion structure stable over extended storage periods while preserving the functional benefits of the water-insoluble liquid.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention changes the interfacial parameters by introducing surfactant, which alters the surface tension and interfacial energy between water and oil phases. This parameter change enables the system to maintain stability over long storage periods while preserving the functional properties of water-insoluble liquid additives.

Inventive Principle:
Principle #35Parameter changes

3Duration of action of stationary object

If water-insoluble liquid is dispersed in water-based ink, then drying property is improved, but odor increases

Engineering Contradiction:
Improvedrying propertyVSAvoidodor
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The invention applies local quality control by selecting specific types of water-insoluble liquids (such as liquid paraffin with high boiling point and low volatility) that provide drying enhancement while having minimal odor. The surfactant also localizes the water-insoluble liquid in fine dispersed droplets, reducing evaporation and odor emission.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The use of chemically inert water-insoluble liquids like liquid paraffin creates an inert environment within the ink formulation that does not readily evaporate or react, thereby maintaining drying properties while minimizing odor generation during storage and usage.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively maintains the dispersion of water-insoluble liquids in the ink, improving drying properties and stability, while also suppressing odor and maintaining ink quality during recording.

Implementation Method 1

a nonionic surfactant and an ionic surfactant having a polarity same as that of the water-soluble colorant; wherein the water-insoluble liquid is dispersed in the water by the nonionic surfactant and the ionic surfactant

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS9580617B2Water-based ink for ink-jet recording, ink cartridge and method for producing water-based ink for ink-jet recording
Publication Date: 2017.02.28 BROTHER KOGYO KK
  • US9580617B2 patent drawing
  • US9580617B2 patent drawing
  • US9580617B2 patent drawing

AI summary

A water-based ink for ink-jet recording includes: a water-soluble colorant; water; a water-insoluble liquid; a nonionic surfactant; and an ionic surfactant having a polarity same as that of the water-soluble colorant. The water-insoluble liquid is dispersed stably in the water by the nonionic surfactant and the ionic surfactant having the polarity same as that of the water-soluble colorant.