Water-Based Polishing Pad for CMP Defect Reduction

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Solution Overview

Problem

Conventional polishing pads for chemical mechanical planarization (CMP) face issues with density and porosity variations, leading to inconsistent polishing performance, delamination, and high manufacturing costs, particularly in the production of 'hard' pads from casting and skiving methods, and 'soft' pads from solvent-based coagulation processes.

Innovation Solution

A water-based polishing pad with a polymeric matrix containing microspheres or porosity, formed from a blend of urethane and acrylic dispersions applied to a permeable substrate, is manufactured using a continuous web-format process, eliminating the need for adhesives and reducing pad-to-pad variations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If casting and skiving method is used to manufacture hard polishing pads, then polishing pad density and porosity can be controlled, but pad-to-pad variations and center-to-edge variations occur leading to inconsistent polishing performance

Engineering Contradiction:
Improvepolishing performance consistencyVSAvoiddensity and porosity uniformity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent changes the manufacturing parameters from batch casting/skiving to continuous web-format coagulation, transforming the production process to eliminate variations. This continuous process maintains consistent density and porosity parameters across all pads, resolving the inconsistency issue.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The web-format coagulation process ensures homogeneous distribution of porosity and density throughout the polishing pad. By forming pads continuously from a uniform polymer solution, the patent achieves homogeneity that eliminates the center-to-edge and pad-to-pad variations inherent in casting methods.

Inventive Principle:
Principle #33Homogeneity

2Manufacturing precision

If solvent-based coagulation process is used to form soft polishing pads, then pad uniformity is improved, but organic solvent handling becomes cumbersome and cost prohibitive

Engineering Contradiction:
Improvepad uniformityVSAvoidsolvent handling complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent changes the solvent parameter from organic (N,N-dimethyl formamide) to water-based polymer dispersions. This parameter change maintains the coagulation process benefits for pad uniformity while eliminating the cumbersome and costly organic solvent handling issues.

Inventive Principle:
Principle #35Parameter changes

3Strength

If pressure-sensitive adhesive is used to bond layers in laminated polishing pads, then layer bonding is achieved, but delamination occurs during polishing due to low bonding strength and marginal chemical resistance

Engineering Contradiction:
Improvelayer bonding strengthVSAvoidresistance to delamination
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent extracts and eliminates the pressure-sensitive adhesive layer from the laminated pad structure. By removing this problematic intermediate layer, the patent avoids the delamination issues while maintaining layer bonding through direct integration of the polishing layer onto the support pad.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses composite materials where the polishing layer and support pad are integrated through direct bonding without adhesive intermediaries. This composite structure provides superior chemical resistance and bonding strength, preventing delamination during polishing operations.

Inventive Principle:
Principle #40Composite materials

4Manufacturing precision

If conventional casting and skiving method is used, then hard polishing pads with consistent reproducible polishing properties can be manufactured, but polishing variations arise from casting location

Engineering Contradiction:
Improvepolishing properties consistencyVSAvoidcasting location dependence
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The patent replaces the mechanical casting and skiving process with a chemical coagulation process in web format. This substitution eliminates the mechanical variations introduced by different casting locations while maintaining consistent and reproducible polishing properties through controlled chemical forming.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a polishing pad with reduced defectivity, improved uniformity, and cost-effectiveness, while enhancing mechanical and chemical adhesion properties, resulting in consistent polishing performance across semiconductor processing applications.

Implementation Method 1

a polymeric matrix having porosity or filler dispersed therein, the polymeric matrix being formed of a blend of a urethane and acrylic dispersion

Methodology Applied
Scientific EffectPhase separation: Phase Change

Implementation Method 2

coagulating polymers utilizing a solvent/non-solvent process to form polishing pads in a web format

Methodology Applied
Scientific EffectCoagulation: Coagulation

Implementation Method 3

the polymeric matrix is applied on a permeable substrate

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentUS8272922B2Method of polishing a substrate
Publication Date: 2012.09.25 DUPONT ELECTRONIC MATERIALS HLDG INC
  • US8272922B2 patent drawing
  • US8272922B2 patent drawing
  • US8272922B2 patent drawing

AI summary

A method for polishing a substrate using a pad comprising, a polymeric matrix having microspheres dispersed therein, the polymeric matrix being formed of a water-based polymer or blends thereof, wherein the polymeric matrix is applied on a permeable substrate, and wherein the polishing pad exhibits reduced defectivity and improved polishing performance are provided.