Water-Based Polyurethane Adhesive Edge Wrapping

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Solution Overview

Problem

Existing water-based adhesives struggle to maintain contact and bond flexible sheet materials, such as polyurethane foams, to substrates with complex and angular geometries, leading to separation during long drying and curing times, especially on plastic substrates like polypropylene and ABS.

Innovation Solution

A water-based, two-component polyurethane dispersion adhesive that can be reactivated by heating, allowing for edge wrapping and providing excellent structural bonding properties, with a solvent-free and low VOC formulation, comprising a solvent-free liquid aliphatic polyisocyanate cross-linker and an anionic polyester polyurethane resin, which can be reactivated multiple times.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water-based adhesives are used for bonding flexible sheet materials to substrates with complex geometries, then VOC emissions are reduced, but the adhesive cannot maintain sufficient contact during drying and curing times

Engineering Contradiction:
ImproveVOC emissionsVSAvoidbonding reliability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The adhesive composition dynamically changes its properties through reactivation heating, transitioning from a cured state to an activated state that allows re-bonding. This enables the adhesive to adapt to different process stages: initial bonding, cooling/storage, and subsequent reactivation for edge wrapping operations.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The adhesive's key parameter - its bonding state - is changed by temperature control. Heating above the reactivation temperature transforms the cured adhesive back into an active bonding state, while cooling maintains it in a stable cured state. This parameter change enables multi-stage processing without sacrificing bonding reliability or increasing VOC emissions.

Inventive Principle:
Principle #35Parameter changes

2Strength

If long drying and curing times are required for water-based adhesives, then bonding strength is achieved, but contact between foam and substrate edges is lost

Engineering Contradiction:
Improvebonding strengthVSAvoiddrying and curing time
Core Design Contradiction:
StrengthVSLoss of time

Solution Approach 1:

The adhesive is applied and initially cured to establish basic bonding strength quickly. The reactivation capability allows subsequent bonding operations to be performed after cooling, eliminating the need to maintain continuous contact during extended curing periods. This preliminary action followed by reactivation enables complex geometry bonding without contact loss.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The bonding process uses periodic heating cycles: initial curing, cooling period, then reactivation heating for edge wrapping. This periodic action allows the adhesive to cycle between cured and active states, enabling multi-stage bonding operations while maintaining overall bonding strength and reducing total process time.

Inventive Principle:
Principle #19Periodic action

3Strength

If the adhesive is cured to maintain bonding strength, then it cannot be reactivated for edge wrapping applications

Engineering Contradiction:
Improvebonding strengthVSAvoidreactivation capability
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The adhesive undergoes reversible phase transitions between cured and activated states through temperature control. Heating above the reactivation temperature causes the cured adhesive to transition back to an active state, enabling edge wrapping. Cooling reverses this transition, restoring bonding strength. This phase transition capability provides both strength and adaptability.

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The adhesive's bonding state is made dynamic through temperature-responsive reactivation. The composition can switch between cured (strong bonding) and activated (re-bonding capable) states as needed. This dynamic behavior enables the adhesive to satisfy both bonding strength requirements and edge wrapping versatility without compromise.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The adhesive achieves strong bonding with a peel strength of 4 kgf to 5 kgf, is environmentally friendly, and allows for edge wrapping applications by reactivating the adhesive, overcoming the limitations of current adhesives in bonding complex geometries and reducing VOC emissions.

Implementation Method 1

applying a first heating cycle to activate the polyurethane adhesive layer on the main surface; applying a second heating cycle to heat the polyurethane adhesive layer on an edge and/or the peripheral surface above the reactivation temperature

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 2

removing water from the applied water-based polyurethane dispersion to form a dried polyurethane adhesive layer on the surfaces

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS12043710B2Two-component, water-based lamination adhesive and use of the same to bond substrates and foams
Publication Date: 2024.07.23 HENKEL KGAA
  • US12043710B2 patent drawing

AI summary

A water comprising, two component polyurethane dispersion adhesive comprising an anionic polyester polyurethane resin and a solvent-free liquid aliphatic polyisocyanate cross-linker. The dispersion can be reactivated one or more times for edge bonding a flexible sheet material onto a substrate having a main surface, a peripheral surface and an edge connecting the main surface and the peripheral surface.