Water-Based Anti-Bonding Coating for Titanium-Steel Rolling

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Solution Overview

Problem

Current high-temperature-resistant titanium-steel anti-bonding coatings are ineffective in preventing titanium-steel bonding during the production of titanium tubes, leading to surface defects, equipment damage, and increased production costs due to the need for frequent equipment grinding and titanium ingot cutting.

Innovation Solution

A water-based high-temperature-resistant titanium-steel anti-bonding coating comprising a film-forming agent, Zn powder, Al2O3 powder, talcum powder, a curing agent, and a dispersant, applied to the steel equipment to form a 0.2-0.4 mm thick film that prevents titanium-steel bonding by forming a dense TiAl3 alloy layer, reducing the TiFe phase formation and allowing continuous production.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional high-temperature-resistant coatings are applied to prevent titanium-steel bonding, then bonding prevention is attempted, but the coating fails to effectively prevent bonding and generates TiFe phase formation

Engineering Contradiction:
Improvebonding prevention effectivenessVSAvoidTiFe phase formation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses a composite coating system consisting of multiple layers: a base coating layer applied to the steel rolling equipment surface, and a titanium oxide-containing coating layer applied over it. This multi-layer composite structure prevents direct contact between titanium and steel, effectively preventing TiFe phase formation while maintaining coating integrity at high temperatures (900°C for 4 hours).

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent introduces titanium oxide (TiO2) as an intermediary substance in the coating composition. This titanium oxide layer acts as a chemical barrier between the titanium ingot and the steel rolling equipment, preventing direct metallurgical bonding and TiFe phase formation while allowing the rolling process to proceed normally.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If the coating is sprayed on the surface of rolling winch made from different materials, then coating application is attempted, but film formation and bonding effect are poor

Engineering Contradiction:
Improvecoating application processVSAvoidfilm formation quality
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent specifies precise coating thickness parameters (0.2-0.4 mm) and applies the coating to specific surfaces (steel rolling equipment contact surfaces). By controlling the coating thickness and application surface, the patent ensures adequate film formation and bonding effectiveness while maintaining ease of application through spray or brush methods.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If titanium ingots are kept in heating furnace at 900°C for more than 4 hours, then rolling preparation is achieved, but titanium becomes sticky to steel equipment causing under-fill defects

Engineering Contradiction:
Improverolling preparation efficiencyVSAvoidsurface quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies the anti-bonding coating to the steel rolling equipment surface before the titanium ingots are heated and rolled. This preliminary protective action ensures that when the titanium is heated to 900°C and becomes sticky, the coating is already in place to prevent bonding, thus maintaining surface quality while enabling the necessary heating and rolling preparation.

Inventive Principle:
Principle #10Preliminary action

4Ease of repair

If equipment is grinded frequently to remove titanium bonding, then equipment maintenance is performed, but production time is lost and costs increase

Engineering Contradiction:
Improveequipment maintenanceVSAvoidproduction interruption
Core Design Contradiction:
Ease of repairVSLoss of time

Solution Approach 1:

The patent employs a consumable coating layer that sacrificially protects the expensive rolling equipment. The coating is designed to be applied periodically rather than requiring frequent equipment grinding and maintenance. This disposable protective layer extends the time between maintenance operations, reducing production interruptions and associated costs.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating effectively prevents titanium-steel bonding, improving the surface quality and yield of titanium tubes, reducing production costs, and enabling continuous rolling without equipment damage, while being environmentally friendly and easy to apply.

Implementation Method 1

forming a dense TiAl3 alloy layer that prevents titanium-steel bonding

Methodology Applied
Scientific EffectMetallurgical reaction: Welding

Implementation Method 2

prevents titanium-steel bonding by forming a dense TiAl3 alloy layer, reducing the TiFe phase formation

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Data Source

PatentUS10640660B2Water-based high-temperature-resistant titanium-steel anti-bonding coating and use thereof
Publication Date: 2020.05.05 PANGANG GROUP RESEARCH INSTITUTE CO LTD

AI summary

The invention relates to a coating for preventing intermetallic bonding, in particular to a water-based high-temperature-resistant titanium-steel anti-bonding coating and its use in the preparation process of titanium ingot. The water-based high-temperature-resistant titanium-steel anti-bonding coating of the invention includes the following components in parts by weight: 50-150 parts of water-based film-forming agent, 0-50 parts of Zn powder, 400-450 parts of Al2O3 powder, and 250-350 parts of talcum powder. The coating of the invention can avoid the bonding reaction with a roller or a winch of the steel equipment in the rolling or perforation process of a titanium tube at 900° C., so as to improve the yield and the production efficiency of titanium material processing. Moreover, the process is simple and easy to operate, the coating is environment-friendly and pollution-free, and easy to prepare.