Water Foreign Substance Detection via Distillation Spectroscopy

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Solution Overview

Problem

Current methods for detecting foreign substances in water, such as endocrine active substances and pollutants, are costly, time-consuming, and require significant personnel and instrument resources, making it difficult to detect leaks or critical contaminations in a timely manner.

Innovation Solution

A method and device utilizing sample preparation by distillation followed by spectroscopic analysis, specifically UV/VIS or fluorescence spectroscopy, with multivariate calibration techniques, to selectively separate and accurately detect foreign substances in water, enabling continuous monitoring with reduced time and resource expenditure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If selective analysis techniques (gas chromatography, liquid chromatography, ICP-MS) are used to detect foreign substances in water, then measurement precision is improved, but productivity deteriorates due to high time consumption and personnel requirements

Engineering Contradiction:
Improvedetection accuracy of foreign substancesVSAvoidanalysis speed
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent extracts and measures multiple foreign substances simultaneously using a single spectroscopic measurement approach, rather than analyzing each substance separately through multiple chromatographic or mass spectrometric methods. This extraction of the core measurement function enables parallel detection of multiple pollutants, significantly improving productivity while maintaining measurement precision through the use of multivariate calibration methods.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The spectroscopic device is designed to detect multiple types of foreign substances (organic compounds, inorganic substances, pesticides, herbicides, fungicides, insecticides, endocrine active substances) using a single universal measurement principle. This multi-functional capability eliminates the need for multiple specialized instruments and methods, thereby improving both productivity and resource efficiency while maintaining accurate detection across different substance classes.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Productivity

If multiple foreign substances are detected simultaneously using spectroscopic methods, then productivity is improved, but measurement precision deteriorates due to interference from water matrix impurities

Engineering Contradiction:
Improvenumber of substances detectedVSAvoiddetection accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent performs preliminary action by conducting a distillation step before spectroscopic measurement to separate and purify the water sample from interfering impurities. This preliminary purification removes humic substances and other matrix components that would otherwise interfere with the spectroscopic detection, thereby maintaining high measurement precision even when detecting multiple foreign substances simultaneously.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent introduces multivariate calibration methods as an intermediary computational step between the raw spectroscopic signal and the final concentration values. These calibration methods mathematically compensate for remaining interferences and enhance the accuracy of foreign substance quantification, acting as a mediator that preserves measurement precision despite the complexity of simultaneous multi-substance detection.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If continuous monitoring is implemented to detect leaks timely, then reliability is improved, but device complexity increases due to required infrastructure

Engineering Contradiction:
Improvetimely detection capabilityVSAvoidmonitoring system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The spectroscopic device is designed to be self-sufficient by integrating all necessary functions (sampling, distillation, spectroscopic measurement, and data evaluation) into a single automated system. The device performs self-calibration and automatic analysis without requiring complex external infrastructure or extensive personnel intervention, thereby achieving reliable continuous monitoring while minimizing device complexity.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces complex mechanical separation and analysis systems (multiple chromatographs, mass spectrometers requiring extensive sample preparation) with a streamlined spectroscopic system that uses optical fields instead of complex mechanical processes. This substitution simplifies the monitoring infrastructure while maintaining reliable detection capability through the use of light-based spectroscopic methods combined with automated distillation and multivariate analysis.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for reliable and cost-effective continuous monitoring of foreign substances in water, reducing analysis time to under an hour and enabling the detection of multiple substances with high accuracy, while minimizing personnel and material costs.

Implementation Method 1

sample preparation by distillation followed by spectroscopic analysis, specifically UV/VIS or fluorescence spectroscopy

Methodology Applied
Scientific EffectDistillation: Distillation

Implementation Method 2

UV/VIS or fluorescence spectroscopy

Methodology Applied
Scientific EffectAbsorption Spectroscopy: Absorption Spectroscopy

Implementation Method 3

UV/VIS or fluorescence spectroscopy

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Data Source

PatentEP2786126B1Method and device for detecting foreign substances in water
Publication Date: 2017.10.11 UNISENSOR SENSORSYST
  • EP2786126B1 patent drawingFigure 1
  • EP2786126B1 patent drawingFigure 2
  • EP2786126B1 patent drawingFigure 3

AI summary

The invention relates to a method for detecting foreign substances, particularly harmful substances, in water, particularly in potable water, preferably suitable for implementation with a device according to one of claims 10-15, comprising the steps a) extraction of a sample, b) preparation of the extracted sample, wherein the preparation of the sample comprises an at least partial distillation of the extracted sample, c) analysis of the prepared sample by means of absorption and/or emission spectroscopy, wherein the analysis comprises the following steps: c1) excitation of the prepared sample with light, particularly a laser or a deuterium lamp, having at least one excitation wave length, and c2) recording of at least one absorption and/or emission spectrum of the light transmitted through the sample and/or of the light emitted by the sample by means of a detector, and d) determination of at least one of the foreign substances in the analysed sample on the basis of at least one of the recorded emission and/or absorption spectra. The invention likewise relates to a corresponding device.