Water-repellant transparent coating-substrate assembly and process for producing the same

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Solution Overview

Problem

Existing water-repellent coatings face issues with uniform silicon oxide fine particle deposition, leading to insufficient adhesion, strength, and reproducibility, as well as a decrease in water repellency due to abrasion and weather resistance.

Innovation Solution

A water-repellent transparent coating-substrate assembly is developed with an inorganic oxide fine particle layer and an overcoating layer, featuring specific irregularities in shape and size, including depressions and protrusions, to enhance adhesion, scratch resistance, and maintain water repellency over time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional water-repellent coating is applied to achieve water repellency, then water repellency is improved, but adhesion and strength are insufficient

Engineering Contradiction:
Improvewater repellencyVSAvoidadhesion and strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies composite materials by combining an inorganic oxide fine particle layer (providing water repellency through fractal structure) with an overcoating layer (providing adhesion and mechanical strength). This multi-layer composite structure resolves the contradiction by assigning different functional properties to different layers, allowing simultaneous achievement of water repellency and structural integrity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The coating is segmented into distinct functional layers: the inorganic oxide fine particle layer responsible for water repellency and the overcoating layer responsible for adhesion and strength. This segmentation allows each layer to be optimized for its specific function without compromising the other, resolving the contradiction between water repellency and mechanical properties.

Inventive Principle:
Principle #1Segmentation

2Reliability

If a water-repellent coating is applied to achieve high water repellency, then water repellency is improved, but scratch resistance and abrasion resistance deteriorate

Engineering Contradiction:
Improvewater repellencyVSAvoidscratch resistance and abrasion resistance
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The composite structure combines the inorganic oxide fine particle layer (providing water repellency) with the overcoating layer (providing scratch and abrasion resistance). The overcoating layer acts as a protective barrier that prevents mechanical damage to the underlying water-repellent structure, thereby maintaining both water repellency and mechanical durability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

By segmenting the coating into specialized layers, the inorganic oxide layer can be optimized for water repellency while the overcoating layer is optimized for mechanical durability. This segmentation allows the water-repellent fractal structure to remain intact and functional while the overcoating provides the necessary scratch and abrasion resistance.

Inventive Principle:
Principle #1Segmentation

3Reliability

If a water-repellent coating is applied to achieve water repellency, then water repellency is improved, but durability against abrasion and weather deteriorates

Engineering Contradiction:
Improvewater repellencyVSAvoiddurability against abrasion and weather
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent creates a composite material system where the inorganic oxide fine particle layer provides water repellency and the overcoating layer provides durability against abrasion and weathering. The overcoating layer serves as a protective barrier that shields the underlying water-repellent structure from environmental degradation, ensuring long-term durability while maintaining water repellency.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The coating is segmented into functional layers with distinct roles: the inorganic oxide layer maintains water repellency through its fractal structure while the overcoating layer provides durability against abrasion and weather. This segmentation ensures that the water-repellent properties are preserved while the overcoating protects against environmental factors over extended periods.

Inventive Principle:
Principle #1Segmentation

4Reliability

If silicon oxide fine particles are deposited to form a coating, then water repellency is improved, but uniformity of deposition and reproducibility deteriorate

Engineering Contradiction:
Improvewater repellencyVSAvoiduniformity of deposition and reproducibility
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The coating process is segmented into multiple steps: first forming the inorganic oxide fine particle layer with controlled fractal structure, then applying the overcoating layer. This segmentation allows precise control over the deposition process and enables better reproducibility by breaking down the complex coating formation into manageable stages with specific parameters for each layer.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coating achieves high water repellency, excellent adhesion, transparency, hardness, and abrasion resistance, making it suitable for applications in automobiles and electronic devices.

Implementation Method 1

a fractal structure enhances the hydrophilicity of a hydrophilic solid surface to change the solid surface to superhydrophilic, and, on the other hand, renders a hydrophobic solid surface superhydrophobic by increasing water repellency

Methodology Applied
Scientific EffectFractal structure: Fractal Forms

Implementation Method 2

the superhydrophobic coating includes projections formed of masses of fine particles and a water-repellent film

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 3

the water-repellent transparent coating having a water contact angle in the range of 130 to 180°

Methodology Applied
Scientific EffectWater contact angle: Surface Tension

Data Source

PatentUS9856407B2Water-repellant transparent coating-substrate assembly and process for producing the same
Publication Date: 2018.01.02 JGC CATALYSTS & CHEMICALS LTD
  • US9856407B2 patent drawing

AI summary

A water-repellent transparent coating-substrate assembly includes a substrate and a water-repellent transparent coating disposed on a surface of the substrate, the transparent coating including an inorganic oxide fine particle layer containing inorganic oxide fine particles, and an overcoating layer disposed on the inorganic oxide fine particle layer, the surface of the water-repellent transparent coating having irregularities including depressions and protrusions in which the protrusions have an average height (TF) in the range of 30 to 500 nm and an average protrusion interval (pitch width) (WF) in the range of 50 to 1000 nm, the water-repellent transparent coating having a water contact angle in the range of 130 to 180°.