Water soluble fibers with post process modifications and articles containing same
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Solution Overview
Problem
Traditional nonwoven water-soluble fibers are non-sustainable, contribute to microplastics, and have disposal issues, with existing methods limiting the adjustment of solubility profiles and properties post-fiber formation, making it difficult to achieve desired solubility and compatibility for various applications.
Innovation Solution
Chemical modification of fibers after formation using modification agents to alter the solubility profile and properties, such as by contacting fibers with agents like glutaric anhydride, maleic anhydride, or phthalic anhydride, to create core-sheath structures or gradients in modification, enhancing solubility, compatibility, and mechanical properties.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Adaptability or versatility
If chemical modifications are made to fiber forming materials to achieve desired solubility profile, then solubility control is improved, but the fiber forming material may not survive the fiber making process
Solution Approach 1:
The patent applies preliminary action by performing chemical modification after fiber formation rather than before. The fibers are first formed using standard processes with unmodified or minimally modified polymers, then subjected to post-formation chemical modification treatments (such as hydrolysis, oxidation, or enzymatic treatment) to achieve the desired solubility profile. This sequence ensures the fiber making process succeeds while still achieving the target solubility characteristics.
2Ease of manufacture
If traditional chemistries are used in nonwoven products, then manufacturing is easier, but the products are non-sustainable and contribute to microplastics
Solution Approach 1:
The patent applies parameter changes by transitioning from traditional petroleum-based polymers to bio-based polymers with controlled solubility characteristics. The key parameter change is the chemical composition of the fiber forming material, using polymers that can be chemically modified to achieve desired solubility profiles while maintaining manufacturing processability. This enables sustainable products that can still be manufactured using conventional nonwoven processes.
3Object-affected harmful factors
If fiber solubility is increased for better disposal, then environmental friendliness is improved, but mechanical properties and bondability may deteriorate
Solution Approach 1:
The patent applies local quality by creating fibers with non-uniform chemical modification distributions. Different regions of the fiber or different fibers within a nonwoven web have different degrees of chemical modification, resulting in varying solubility characteristics. This allows the product to maintain adequate mechanical properties in regions with lower modification while achieving good solubility and disposal characteristics in regions with higher modification, or to achieve controlled disintegration patterns.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
Enables control over solubility and mechanical properties, allowing for flexible composition and processability, improved bonding, and triggered delivery of active agents, while promoting sustainable and hygienic disposal of nonwoven products.
Implementation Method 1
chemical modification of fibers after formation using modification agents to alter the solubility profile and properties
Implementation Method 2
contacting fibers with agents like glutaric anhydride, maleic anhydride, or phthalic anhydride, to create core-sheath structures or gradients in modification
Data Source
AI summary
Methods of treating fibers comprising a polymer including at least one of a vinyl acetate moiety or a vinyl alcohol moiety, and resulting fibers or the products comprising the resulting fibers are disclosed. In an example embodiment, a fiber having a surface region and an interior region, includes a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified with a modification agent. The fiber has a transverse cross-section including the interior region comprising the polymer having a first degree of modification and the surface region comprising the polymer having a second degree of modification greater than the first degree of modification.


