Water-Soluble Unit Dose Suds Generation via Surfactant Optimization

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Solution Overview

Problem

Water-soluble unit dose articles exhibit poor suds generation compared to powder compositions, which affects consumer perception of their cleaning ability.

Innovation Solution

A water-soluble unit dose article comprising a fibrous non-woven sheet forming a sealed compartment with a granular laundry detergent composition, where the detergent includes a surfactant system of linear alkylbenzene sulphonate and alkyl alkoxylated alcohol, enhancing suds generation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If water-soluble unit dose article uses conventional detergent formulation, then convenience and ease of use are improved, but suds generation deteriorates

Engineering Contradiction:
Improveconvenience and ease of useVSAvoidsuds generation
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent applies parameter changes by modifying the surfactant system composition parameters - specifically using linear alkylbenzene sulphonate combined with alkyl alkoxylated alcohol (average degree of alkoxylation 1-10) in a weight ratio of 3:1 to 300:1. This parameter optimization resolves the contradiction by achieving both water solubility (maintaining convenience) and improved suds generation (increasing from poor to good performance comparable to powder compositions).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating a surfactant system that combines linear alkylbenzene sulphonate (anionic surfactant) with alkyl alkoxylated alcohol (non-ionic surfactant). This composite surfactant system leverages the synergistic effects of both surfactant types to achieve superior suds generation while maintaining the water-soluble characteristics necessary for unit dose article functionality.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If water-soluble unit dose article uses powder composition formulation, then suds generation is improved, but convenience and ease of use deteriorates

Engineering Contradiction:
Improvesuds generationVSAvoidconvenience and ease of use
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent resolves this contradiction by changing the physical state parameter of the detergent from powder to water-soluble granular form, while simultaneously optimizing the chemical composition parameters (surfactant system with linear alkylbenzene sulphonate and alkyl alkoxylated alcohol). This allows the product to maintain powder-like suds generation performance while achieving the convenience of water-soluble unit dose articles.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If water-soluble sheet dissolves completely, then ease of use is improved, but suds generation deteriorates

Engineering Contradiction:
Improveease of useVSAvoidsuds generation
Core Design Contradiction:
Ease of operationVSQuantity of substance

Solution Approach 1:

The patent resolves this contradiction by changing the detergent composition parameters - specifically formulating a granular laundry detergent with a optimized surfactant system (linear alkylbenzene sulphonate combined with alkyl alkoxylated alcohol in 3:1 to 300:1 weight ratio). This composition change enables complete dissolution (maintaining ease of use) while achieving good suds generation (resolving the performance issue).

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining different surfactant types (anionic linear alkylbenzene sulphonate and non-ionic alkyl alkoxylated alcohol) in a synergistic formulation. This composite approach ensures that the detergent fully dissolves in water (maintaining ease of use) while the surfactant combination produces adequate suds generation.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively improves suds generation in water-soluble unit dose articles, matching the performance of traditional powder compositions and addressing consumer concerns about cleaning efficacy.

Implementation Method 1

the water-soluble sheet dissolves and/or disintegrates and releases the detergent composition into the water

Methodology Applied
Scientific EffectWater solubility: Solvation

Implementation Method 2

the granular laundry detergent comprises from 1wt% to 50wt% of a surfactant system, wherein the surfactant system comprises linear alkylbenzene sulphonate and alkyl alkoxylated alcohol

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Data Source

PatentEP4234666A1Water-soluble unit dose article comprising a fibrous non-woven sheet and a surfactant system
Publication Date: 2023.08.30 PROCTER & GAMBLE CO
  • EP4234666A1 patent drawingFigure 1~2
  • EP4234666A1 patent drawing
  • EP4234666A1 patent drawing

AI summary

A water-soluble unit dose article comprising a fibrous non-woven sheet and a surfactant system.