Waterborne Shape Memory Coatings for Reversible Multi-Substrate Use

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Solution Overview

Problem

Conventional shape memory textiles and coatings face challenges such as short-lasting effects, chemical damage to hair, and the use of volatile and irritant cross-linkers, limiting their application to specific substrates and requiring complex processes for shape changes.

Innovation Solution

Development of waterborne shape memory polymer coatings that can be applied as an aqueous dispersion, incorporating switching segments, ionically charged groups, and crosslinkable units, allowing for reversible shape memory effects on various substrates, including hair, textiles, and paper products, triggered by heat, light, or water exposure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of moving object

If conventional shape memory textiles and coatings are used, then shape memory effect is achieved, but the effect is short-lasting and requires frequent reapplication

Engineering Contradiction:
Improveduration of shape memory effectVSAvoidlong-lasting effect
Core Design Contradiction:
Duration of action of moving objectVSReliability

Solution Approach 1:

The patent modifies the chemical composition and molecular structure of shape memory polymers to enhance the stability and longevity of the shape memory effect. By adjusting parameters such as cross-linking density, polymer chain architecture, and functional group composition, the coating achieves prolonged duration of action and improved reliability for long-lasting effects.

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If volatile and irritant cross-linkers are used, then cross-linking reaction occurs, but health hazards and environmental pollution are caused

Engineering Contradiction:
Improvecross-linking processVSAvoidhealth hazard
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent replaces volatile and irritant cross-linkers with water-based or environmentally benign cross-linking systems. This substitution eliminates harmful vapors and health hazards while maintaining effective cross-linking reactions, creating a safer manufacturing environment and reducing environmental pollution.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent employs water-soluble cross-linking agents that can be easily rinsed away or decompose harmlessly, replacing persistent toxic cross-linkers. This approach allows for effective cross-linking during manufacturing while eliminating long-term health and environmental risks.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Adaptability or versatility

If shape memory coatings are applied to diverse substrates, then versatility is improved, but coating formulation complexity increases

Engineering Contradiction:
Improveapplicability to various substratesVSAvoidcoating formulation
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent develops a universal waterborne shape memory polymer coating formulation that can be applied to multiple substrate types including hair, textiles, and paper products. The coating contains functional groups and adhesion promoters that enable broad substrate compatibility without requiring separate formulations for each application, thereby improving versatility while controlling formulation complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The waterborne shape memory polymer coatings provide long-lasting, reversible, and harmless shape memory effects on diverse substrates, enhancing their performance and applicability, with applications in hair care, textiles, and paper products, and enabling self-repairable and water-sensitive functionalities.

Implementation Method 1

SMP's are responsive polymers comprising cross-linked network polymer backbones where the polymer backbones between cross-linking junctions are crystallizable or glassy and can behave as 'switching segment.' SMP's can be fixed into a deformed temporary shape and later recover to a permanent shape memorized by the cross-linked network structure upon a stimulus, most commonly heat

Methodology Applied
Scientific EffectPhase transition: Phase Change

Implementation Method 2

For the dispersibility in water, charging groups are incorporated into the polymer chains

Methodology Applied
Scientific EffectElectrostatic interaction: Electrostatics

Implementation Method 3

SMP's are responsive polymers comprising cross-linked network polymer backbones

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Data Source

PatentUS9982163B2Waterborne shape memory polymer coatings
Publication Date: 2018.05.29 SYRACUSE UNIVERSITY
  • US9982163B2 patent drawing
  • US9982163B2 patent drawing
  • US9982163B2 patent drawing

AI summary

The present invention relates to shape memory polymers and waterborne coating materials and, more particularly, to waterborne shape memory polymer coatings.