Wavelength Converting Component Using Ceramizable Silazane Matrix

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Solution Overview

Problem

Current matrix materials for embedding wavelength converting materials in LEDs face challenges such as poor barrier properties, thermal stability, mechanical stability, and compatibility with various wavelength converting materials, particularly under high temperature and radiation conditions, leading to issues like degradation, discolouration, and limited shape complexity.

Innovation Solution

A method involving a dispersion of crosslinkable ceramizable materials with silazane repeating units, cured at temperatures between 250°C to 500°C, forming a semi-ceramic matrix with Si—N bonds, which provides improved thermal conductivity, mechanical stability, and compatibility with various wavelength converting materials, allowing for complex shapes and enhanced durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If ceramic platelets are used as wavelength converting components, then thermal stability is improved, but manufacturing difficulty increases and shape complexity is limited

Engineering Contradiction:
Improvethermal stabilityVSAvoidmanufacturing difficulty
Core Design Contradiction:
Stability of the object's compositionVSEase of manufacture

Solution Approach 1:

The invention changes the manufacturing parameters from high-temperature sintering (>1000°C) to low-temperature curing (250-500°C) by using crosslinkable ceramizable materials. This parameter change enables thermal stability comparable to ceramics while dramatically simplifying the manufacturing process and allowing complex geometries to be achieved through molding techniques.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite materials consisting of crosslinkable ceramizable materials combined with wavelength converting materials. This composite approach provides the thermal stability of ceramic materials while maintaining the ease of manufacture and shape flexibility of polymer-based materials, resolving the contradiction between thermal performance and manufacturing complexity.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If high sintering temperatures are used for ceramic platelets, then thermal stability is improved, but compatibility with certain wavelength converting materials deteriorates due to decomposition

Engineering Contradiction:
Improvethermal stabilityVSAvoidmaterial compatibility
Core Design Contradiction:
Stability of the object's compositionVSAdaptability or versatility

Solution Approach 1:

The invention changes the processing temperature parameter from high-temperature sintering (>1000°C) to low-temperature curing (250-500°C). This parameter change preserves the thermal stability of the final product while preventing thermal decomposition of sensitive wavelength converting materials such as silicate and nitride phosphors during manufacturing, thereby improving material compatibility.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional binder materials are used for embedding wavelength converting material, then ease of manufacture is improved, but thermal stability deteriorates due to decomposition under high temperature

Engineering Contradiction:
Improveease of manufactureVSAvoidthermal stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The invention replaces conventional organic binder materials with crosslinkable ceramizable materials that form a semi-ceramic matrix upon curing. This composite material approach maintains the ease of manufacture associated with binder-based systems while achieving the thermal stability of ceramic materials, as the cured matrix can withstand high temperatures without decomposition.

Inventive Principle:
Principle #40Composite materials

4Stability of the object's composition

If ceramic platelets are used, then thermal stability is improved, but shape complexity is limited to plain geometries

Engineering Contradiction:
Improvethermal stabilityVSAvoidshape complexity
Core Design Contradiction:
Stability of the object's compositionVSShape

Solution Approach 1:

The invention changes the processing method from sintering (which limits shape complexity) to molding and curing processes. This parameter change enables the production of wavelength converting components with complex geometries including protrusions and recesses, while maintaining the thermal stability achieved through the ceramizable material composition.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves stable colour point conversion of blue, violet, and UV light to longer wavelengths with improved thermal conductivity and mechanical stability, maintaining performance under high power LED conditions without thermal decomposition or discolouration, and allows for complex geometries and broad compatibility with wavelength converting materials.

Implementation Method 1

curing said dispersion at a temperature of >250 to ≤500° C. to obtain a wavelength converting component

Methodology Applied
Scientific EffectCrosslinking:

Implementation Method 2

a crosslinkable ceramizable material and at least one wavelength converting material... curing said dispersion... to obtain a wavelength converting component

Methodology Applied
Scientific EffectCeramization:

Implementation Method 3

The wavelength converting component of the present invention can be used for converting blue, violet and/or UV light into light with a longer wavelength

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS11466839B2Wavelength converting component
Publication Date: 2022.10.11 MERCK PATENT GMBH
  • US11466839B2 patent drawing
  • US11466839B2 patent drawing
  • US11466839B2 patent drawing

AI summary

The present invention relates to a manufacturing method for a wavelength converting component which is prepared from a dispersion containing a crosslinkable ceramizable polymer material having a silazane repeating unit and at least one wavelength converting material. There are further provided wavelength converting components which can be used for converting blue, violet and/or UV light into light with a longer wavelength. There is also provided a light source and a lighting unit comprising said wavelength converting components.