Wavelength Converting Material Oxygen-Filled Lattice Efficiency
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Solution Overview
Problem
Current wavelength converting materials for light-emitting devices, such as phosphors, often suffer from atom deficits in their host lattice, leading to loose bonding and reduced conversion efficiency, especially when additional space is not available to accommodate extra bivalent metal atoms, resulting in inefficient light conversion across the visible spectrum.
Innovation Solution
A wavelength converting material with a modified crystal lattice structure, where vacancies are filled with oxygen atoms, enhancing the rigidity of the host lattice and improving conversion efficiency, is developed. The material is represented by the formula R3-x-y-zAx+yMzSi6-w1Alw1O3x+y+w1N11-7/3-y-w1, with specific constraints on the values of x, y, z, and w1, and occupancy by trivalent rare-earth and bivalent metal elements, along with charge compensation by replacing Si and N with Al and O.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Loss of energy
If vacancies in the host lattice are left empty or filled with non-oxygen atoms, then the crystal structure maintains simpler composition, but the bonding becomes loose and conversion efficiency decreases
Solution Approach 1:
The patent applies parameter changes by systematically varying the substitution parameters (x, y, z, w1, w2) in the crystal lattice formula to optimize the balance between structural complexity and conversion efficiency. Specifically, it adjusts the ratios of rare-earth elements (R), metal elements (M), and bivalent metal elements (A) along with their substitution levels to achieve maximum photometric efficiency while maintaining a manageable crystal structure.
Solution Approach 2:
The patent employs composite materials by creating a multi-element doped crystal lattice that combines rare-earth elements (for luminescence), metal elements (for structural stability), and bivalent metal elements (for charge compensation). This composite approach within the host lattice enables simultaneous optimization of bonding strength, charge balance, and light conversion efficiency that single-element doping cannot achieve.
2Stability of the object's composition
If additional bivalent metal atoms are added to compensate for charge imbalance, then charge compensation is improved, but there is no space available in the host lattice to accommodate them
Solution Approach 1:
The patent applies local quality by creating specific substitution sites within the crystal lattice where bivalent metal elements (A) replace trivalent rare-earth elements (R) at defined positions (indicated by parameter x). This localized substitution strategy allows charge compensation to occur at specific lattice locations without requiring uniform expansion of the entire host lattice volume, thus accommodating charge balance needs within existing spatial constraints.
Solution Approach 2:
The patent utilizes another dimension by introducing multiple substitution parameters (x, y, z, w1, w2) that operate independently along different compositional dimensions. This multi-dimensional parameter space allows the formulation to achieve charge compensation through coordinated substitutions across different element positions and types, effectively using compositional complexity in multiple dimensions rather than requiring increased physical volume.
3Reliability
If oxygen atoms are used to fill vacancies and compensate for atom deficits, then bonding rigidity is enhanced and conversion efficiency improves, but the manufacturing process becomes more complex
Solution Approach 1:
The patent applies preliminary action by incorporating oxygen into the host lattice during the epitaxial growth process itself, rather than requiring subsequent post-processing steps. The oxygen is introduced in controlled amounts during MOCVD or MBE growth to fill vacancies and form stable oxide bonds, ensuring proper stoichiometry is achieved during the primary manufacturing process and eliminating the need for complex secondary oxygen treatment steps.
Solution Approach 2:
The patent replaces mechanical/physical post-processing methods with a chemical approach during epitaxial growth. Instead of using mechanical mixing or physical diffusion to incorporate oxygen after growth, the method uses chemical vapor deposition to directly incorporate oxygen atoms into the lattice during growth, substituting a chemical process for what would otherwise require complex mechanical or thermal post-treatment operations.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The modified material exhibits increased conversion efficiency and spectral red shifting of absorption and emission bands, leading to improved color rendition and luminous efficiency in light-emitting devices, with potential for reduced sintering temperatures and enhanced mechanical properties.
Implementation Method 1
A light emitting device such as an LED is often combined with a wavelength converting material such as a phosphor
Data Source
AI summary
Embodiments of the invention include a wavelength-converting composition as defined by R3-x-y-zAx+yMzSi6-w1Alw1O3x+y+w1N11-7x/3-y-w1□2-2x/3, with □ being vacancies of the structure that are filled by oxygen atoms with 0<x≤3, −3≤y<3, 0<z<1,0≤w1≤6, 0≤x+y, x+y+z≤3, 11−7/3x−y−w1≤0, and 3x+y+w1≤13. R is selected from the group comprising trivalent La, Gd, Tb, Y, Lu; A is selected from the group comprising bivalent Ca, Mg, Sr, Ba, and Eu; and M is selected from the group comprising trivalent Ce, Pr and Sm.


