Wavelength Converting Material Oxygen-Filled Lattice Efficiency

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Solution Overview

Problem

Current wavelength converting materials for light-emitting devices, such as phosphors, often suffer from atom deficits in their host lattice, leading to loose bonding and reduced conversion efficiency, especially when additional space is not available to accommodate extra bivalent metal atoms, resulting in inefficient light conversion across the visible spectrum.

Innovation Solution

A wavelength converting material with a modified crystal lattice structure, where vacancies are filled with oxygen atoms, enhancing the rigidity of the host lattice and improving conversion efficiency, is developed. The material is represented by the formula R3-x-y-zAx+yMzSi6-w1Alw1O3x+y+w1N11-7/3-y-w1, with specific constraints on the values of x, y, z, and w1, and occupancy by trivalent rare-earth and bivalent metal elements, along with charge compensation by replacing Si and N with Al and O.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If vacancies in the host lattice are left empty or filled with non-oxygen atoms, then the crystal structure maintains simpler composition, but the bonding becomes loose and conversion efficiency decreases

Engineering Contradiction:
Improveconversion efficiencyVSAvoidcrystal lattice structure
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by systematically varying the substitution parameters (x, y, z, w1, w2) in the crystal lattice formula to optimize the balance between structural complexity and conversion efficiency. Specifically, it adjusts the ratios of rare-earth elements (R), metal elements (M), and bivalent metal elements (A) along with their substitution levels to achieve maximum photometric efficiency while maintaining a manageable crystal structure.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by creating a multi-element doped crystal lattice that combines rare-earth elements (for luminescence), metal elements (for structural stability), and bivalent metal elements (for charge compensation). This composite approach within the host lattice enables simultaneous optimization of bonding strength, charge balance, and light conversion efficiency that single-element doping cannot achieve.

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If additional bivalent metal atoms are added to compensate for charge imbalance, then charge compensation is improved, but there is no space available in the host lattice to accommodate them

Engineering Contradiction:
Improvecharge compensationVSAvoidhost lattice space
Core Design Contradiction:
Stability of the object's compositionVSVolume of stationary object

Solution Approach 1:

The patent applies local quality by creating specific substitution sites within the crystal lattice where bivalent metal elements (A) replace trivalent rare-earth elements (R) at defined positions (indicated by parameter x). This localized substitution strategy allows charge compensation to occur at specific lattice locations without requiring uniform expansion of the entire host lattice volume, thus accommodating charge balance needs within existing spatial constraints.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent utilizes another dimension by introducing multiple substitution parameters (x, y, z, w1, w2) that operate independently along different compositional dimensions. This multi-dimensional parameter space allows the formulation to achieve charge compensation through coordinated substitutions across different element positions and types, effectively using compositional complexity in multiple dimensions rather than requiring increased physical volume.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Reliability

If oxygen atoms are used to fill vacancies and compensate for atom deficits, then bonding rigidity is enhanced and conversion efficiency improves, but the manufacturing process becomes more complex

Engineering Contradiction:
Improvebonding rigidityVSAvoidmanufacturing process
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by incorporating oxygen into the host lattice during the epitaxial growth process itself, rather than requiring subsequent post-processing steps. The oxygen is introduced in controlled amounts during MOCVD or MBE growth to fill vacancies and form stable oxide bonds, ensuring proper stoichiometry is achieved during the primary manufacturing process and eliminating the need for complex secondary oxygen treatment steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces mechanical/physical post-processing methods with a chemical approach during epitaxial growth. Instead of using mechanical mixing or physical diffusion to incorporate oxygen after growth, the method uses chemical vapor deposition to directly incorporate oxygen atoms into the lattice during growth, substituting a chemical process for what would otherwise require complex mechanical or thermal post-treatment operations.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified material exhibits increased conversion efficiency and spectral red shifting of absorption and emission bands, leading to improved color rendition and luminous efficiency in light-emitting devices, with potential for reduced sintering temperatures and enhanced mechanical properties.

Implementation Method 1

A light emitting device such as an LED is often combined with a wavelength converting material such as a phosphor

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS11041122B2Wavelength converting material for a light emitting device
Publication Date: 2021.06.22 LUMILEDS SINGAPORE PTE LTD
  • US11041122B2 patent drawing
  • US11041122B2 patent drawing
  • US11041122B2 patent drawing

AI summary

Embodiments of the invention include a wavelength-converting composition as defined by R3-x-y-zAx+yMzSi6-w1Alw1O3x+y+w1N11-7x/3-y-w1□2-2x/3, with □ being vacancies of the structure that are filled by oxygen atoms with 0<x≤3, −3≤y<3, 0<z<1,0≤w1≤6, 0≤x+y, x+y+z≤3, 11−7/3x−y−w1≤0, and 3x+y+w1≤13. R is selected from the group comprising trivalent La, Gd, Tb, Y, Lu; A is selected from the group comprising bivalent Ca, Mg, Sr, Ba, and Eu; and M is selected from the group comprising trivalent Ce, Pr and Sm.