WDS Spectrum Mapping by Scanning Analyzing Element Positions

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Solution Overview

Problem

Wavelength-dispersive X-ray spectrometers (WDS) face challenges in acquiring spectrum maps efficiently, as they can only analyze one energy value at a time, limiting their ability to easily produce spectrum maps compared to energy-dispersive X-ray spectrometers (EDS), which can measure all elements simultaneously.

Innovation Solution

An analyzing method and analyzer that utilize a wavelength-dispersive X-ray spectrometer with an electron optical system and a control unit to repeatedly perform mapping analysis while changing the position of the analyzing element, acquiring multiple map data sets and generating a spectrum map that associates positions on the specimen with X-ray spectra.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If wavelength-dispersive X-ray spectrometer performs mapping analysis to acquire map data, then measurement precision is improved, but productivity deteriorates due to inability to analyze multiple energies simultaneously

Engineering Contradiction:
Improveenergy resolutionVSAvoiddata collection time
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent divides the spectrum acquisition process into multiple mapping analysis steps, each targeting a specific energy range. By segmenting the full spectrum into multiple energy windows and acquiring map data for each segment separately, the system maintains high measurement precision while enabling comprehensive multi-element analysis through systematic data collection and synthesis.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary mapping analysis to acquire map data for multiple energy ranges before generating the final spectrum map. This preliminary action of collecting element distribution data across different energy windows enables subsequent reconstruction of complete X-ray spectra at each spatial position, resolving the contradiction between precise measurement and efficient productivity.

Inventive Principle:
Principle #10Preliminary action

2Measurement precision

If wavelength-dispersive X-ray spectrometer performs point analysis to acquire spectrum map, then measurement precision is improved, but loss of time increases due to repeated analysis at each position

Engineering Contradiction:
Improveenergy resolutionVSAvoidanalysis time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent segments the spectrum acquisition into multiple mapping analysis operations, each covering a specific energy range. By performing mapping analysis that scans the specimen while detecting X-rays at multiple energies simultaneously, the system avoids repeated point analysis at each position, thereby maintaining high measurement precision while significantly reducing total analysis time.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent performs preliminary mapping analysis to acquire element distribution data across multiple energy ranges before generating the final spectrum map. This preliminary collection of spatially-resolved spectral data eliminates the need for repeated point analysis, resolving the contradiction between precise measurement and time efficiency.

Inventive Principle:
Principle #10Preliminary action

3Adaptability or versatility

If wavelength-dispersive X-ray spectrometer uses multiple analyzing elements, then adaptability is improved, but device complexity increases

Engineering Contradiction:
Improvemulti-element analysis capabilityVSAvoidanalyzer structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent segments the spectral analysis into multiple energy ranges, with each analyzing element optimized for a specific energy window. This segmentation allows the system to achieve high adaptability for multi-element analysis by assigning specific elements to specific detectors, while the modular segmented structure actually reduces overall device complexity compared to attempting simultaneous full-spectrum detection with a single complex system.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Facilitates the acquisition of spectrum maps using WDS, allowing for simultaneous analysis of multiple elements and reducing the time required for data collection compared to traditional point analysis methods, while also enabling corrections for spectrum shifts due to specimen displacement and electron beam deflection.

Implementation Method 1

a wavelength-dispersive X-ray spectrometer that has an analyzing element to analyze an X-ray emitted from a specimen and detects an X-ray of energy corresponding to a position of the analyzing element

Methodology Applied
Scientific EffectX-ray diffraction: Bragg Diffraction

Implementation Method 2

an electron optical system that irradiates a specimen with an electron beam

Methodology Applied
Scientific EffectElectron impact excitation: Electron Impact Desorption

Data Source

PatentEP4365580A1Wavelength-dispersive x-ray spectrometer analyzing method and analyzer
Publication Date: 2024.05.08 JEOL LTD
  • EP4365580A1 patent drawingFigure 1~2
  • EP4365580A1 patent drawingFigure 3~4
  • EP4365580A1 patent drawingFigure 5~6

AI summary

An analyzing method using an analyzer including a wavelength-dispersive X-ray spectrometer (50a) that has an analyzing element (52) to analyze an X-ray emitted from a specimen (S) and detects an X-ray of energy corresponding to a position of the analyzing element (52), the analyzing method includes: acquiring a plurality of map data by repeatedly performing a mapping analysis while changing the position of the analyzing element (52), the mapping analysis being an analysis to detect an X-ray of specific energy with the position of the analyzing element (52) fixed to acquire map data while scanning the specimen with an electron beam (EB); and generating, based on the plurality of map data, a spectrum map (SM) in which a position on the specimen (S) and an X-ray spectrum are associated with each other.