Weak-Acid Concrete Stain With Self-Neutralizing Color Chemistry

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Solution Overview

Problem

Existing methods for coloring concrete surfaces using acidic solutions are hazardous due to the use of corrosive chemicals, leading to temporary and prone-to-peeling results, with high labor and expense costs for cleanup and application.

Innovation Solution

A composition combining an acid with a weak base, such as hydrogen chloride and urea, which self-neutralizes during the staining process, eliminating the need for additional neutralization steps and reducing corrosive risks, while using water-soluble metallic salts to impart color to cementitious substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If highly corrosive acidic solutions are used to color concrete surfaces, then the coloring becomes permanent and durable, but the handling safety deteriorates and harmful factors increase

Engineering Contradiction:
Improvecoloring permanenceVSAvoidcorrosive hazard
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent introduces an intermediary substance (weak base) that mediates between the acid and the concrete surface. This weak base reacts with the acid to form a salt that serves as the actual staining agent, eliminating the need to handle concentrated corrosive acids while maintaining the permanent coloring effect through the same chemical reaction with calcium carbonate.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical parameters of the staining solution by using pre-formed salts instead of acidic solutions. This parameter change transforms the solution from highly corrosive (low pH) to non-corrosive (neutral or near-neutral pH), while the salt components maintain the ability to react with calcium carbonate and impart permanent color.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional acid staining methods are used, then permanent coloring is achieved, but extensive cleanup and neutralization steps are required

Engineering Contradiction:
Improvecoloring permanenceVSAvoidcleanup time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent employs self-service through the self-neutralization property of the weak base components in the staining solution. The weak base automatically neutralizes any excess acid during the staining process, eliminating the need for separate neutralization steps and reducing cleanup time and complexity.

Inventive Principle:
Principle #25Self-service

3Ease of manufacture

If corrosive acids are used for concrete staining, then effective coloring is achieved, but additional safety equipment and handling procedures are needed

Engineering Contradiction:
Improvestaining effectivenessVSAvoidsafety equipment requirements
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent replaces expensive and complex safety equipment requirements with a simple, disposable-like approach by using pre-formulated non-corrosive staining solutions. These solutions achieve the same staining effectiveness without requiring specialized safety equipment, making the process as easy to implement as conventional painting or staining methods.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a safe, durable, and permanent coloring process for concrete surfaces, reducing the need for extensive cleanup and neutralization, and offering a range of color options with improved safety and reduced costs.

Implementation Method 1

the use of hydrochloric acid to decompose the calcium carbonate and calcium oxide in the concrete, and to facilitate the ion exchange with the metallic salt, which imparts the color to the surface of the material

Methodology Applied
Scientific EffectIon exchange: Ion Exchange

Implementation Method 2

The calcium carbonate in the mixture is insoluble in water but reacts readily with most acids

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

A second common method in the art of coloring concrete involves washing the concrete surface with an acidic solution to roughen or etch the surface; neutralize and rinse away the etching solution with a mixture of common baking soda and water

Methodology Applied
Scientific EffectDecomposition: Decomposition (biological)

Data Source

PatentUS8460399B2Weak acid based concrete stain
Publication Date: 2013.06.11 SWIMC LLC

AI summary

The present invention provides compositions and methods which are adapted to impart color to concrete or mineral substrate surfaces. Specifically, the present invention relates to a composition and methods adapted to treat concrete surfaces which have the advantage of using a non-corrosive acid-based solution.