Wear-Resistant Inkjet Coating via Nanoparticle Dispersion
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Solution Overview
Problem
Inkjet inks with low viscosity containing inorganic particles face challenges in being discharged and coated effectively due to increased viscosity and particle aggregation, leading to clogging issues and printing failures.
Innovation Solution
A laminate with a wear-resistant layer formed using a low-viscosity radiation-curable ink containing inorganic nanoparticles and a compound represented by Formula (1), which reduces viscosity and prevents aggregation, enabling printing methods like inkjet printing, gravure coating, or bar coating.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If inorganic particles are contained in an ink to impart wear resistance to a protection layer, then wear resistance is improved, but the viscosity of the ink increases making it unsuitable for inkjet printing and other low-viscosity coating methods
Solution Approach 1:
The patent changes the particle size parameter of inorganic particles from conventional larger sizes to nanometer scale (1-100 nm), which fundamentally alters the ink's flow properties. This parameter change enables the ink to maintain low viscosity suitable for inkjet printing while still providing wear resistance when cured, as the nanoscale particles can be dispersed uniformly without significantly increasing viscosity.
Solution Approach 2:
The patent creates a composite ink formulation combining inorganic nanoparticles with specific organic components including polymerizable monomers, polymerizable oligomers, and photopolymerization initiators. This composite structure allows the ink to exhibit both low viscosity for easy application and high wear resistance after curing, as the inorganic nanoparticles provide hardness while the organic matrix provides flowability.
2Strength
If inorganic particles are contained in an ink to provide wear resistance, then the protection layer gains durability, but the inorganic particles aggregate causing clogging of discharging nozzles and wire coating rolls
Solution Approach 1:
The patent changes the particle size parameter to nanometer scale (1-100 nm), which prevents aggregation and clogging. The extremely small size allows particles to remain suspended uniformly in the ink without settling or clumping, enabling reliable passage through inkjet nozzles and wire coating rolls while still providing effective wear resistance after the layer is formed and cured.
Solution Approach 2:
The patent introduces surfactants and dispersants as intermediary substances that mediate between the inorganic particles and the ink medium. These intermediaries prevent particle aggregation by providing steric or electrostatic repulsion, ensuring uniform dispersion and preventing clogging of coating equipment while maintaining the wear-resistant properties of the inorganic particles.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution allows for the successful application of a wear-resistant layer with reduced viscosity, preventing clogging and ensuring effective printing while maintaining wear resistance and flexibility.
Implementation Method 1
a wear-resistant layer containing a cured product of a radiation-curable ink
Data Source
Figure 1
Figure 2A~2C
Figure 3A~3C
AI summary
To provide a laminate having an inorganic nanoparticle -containing wear-resistant layer formed by low viscosity ink and an inorganic nanoparticle -containing radiation-curable ink having low viscosity. A laminate according to an embodiment of the present disclosure contains: a substrate, and a wear-resistant layer containing a cured product of a radiation-curable ink, the radiation-curable ink containing inorganic nanoparticles, a compound represented by Formula (1) below, and at least one selected from the group consisting of a radiation-curable polymerizable oligomer and a radiation-curable polymerizable monomer: R1-R2-Si(OR3)3 Formula (1). In Formula (I), R1 is an acryloyl group or a methacryloyl group, R2 is an alkylene group having from 5 to 12 carbon atoms, and R3 is an alkyl group having from 1 to 4 carbon atoms..