Tubular Welding Electrode Sulfur Magnesium Oxide Crack Resistance

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Solution Overview

Problem

Steel wire electrodes with high sulfur content in the flux exhibit improved liquid metal wetting but are prone to cracking after weld metal solidification, necessitating enhanced crack resistance.

Innovation Solution

Incorporating magnesium oxide into the granular powder flux fill core of tubular welding electrodes, alongside a sulfur source like iron sulfide, to balance wetting properties and reduce cracking probability without affecting mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high amounts of sulfur source are added to the flux, then liquid metal wetting properties are dramatically improved, but crack resistance deteriorates

Engineering Contradiction:
Improveliquid metal wetting propertiesVSAvoidcrack resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

Magnesium oxide is introduced as an intermediary substance that mediates between sulfur and the weld metal. The MgO reacts with sulfur to form magnesium sulfide, controlling the release and interaction of sulfur with molten metal. This intermediary action allows sulfur to improve wetting properties while preventing excessive sulfur from causing cracking in the solidified weld metal.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent optimizes the concentration parameters of both sulfur source (0.01-0.1 wt.%) and magnesium oxide (0.5-4.0 wt.%) in the flux. By precisely controlling these compositional parameters and their ratio, the flux achieves optimal sulfur release characteristics that improve wetting while limiting crack formation. The parameter optimization ensures sulfur is released at controlled rates and concentrations.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If high amounts of sulfur source are added to the flux, then wetting performance is improved regardless of surface cleanliness, but cracking probability increases after weld metal solidifies

Engineering Contradiction:
Improvewetting performance on clean and dirty surfacesVSAvoidcrack resistance after solidification
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

Magnesium oxide serves as a mediator that controls sulfur's interaction with weld metal. The MgO-S reaction system regulates sulfur availability, allowing sufficient sulfur to be present for improved wetting on various surface conditions while preventing sulfur-induced cracking during solidification through controlled sulfur release kinetics.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical composition parameters of the flux by adding magnesium oxide at specific concentrations (0.5-4.0 wt.%). This compositional change alters the sulfur release behavior, enabling the flux to provide consistent wetting performance across different surface conditions while maintaining crack resistance through optimized sulfur concentration and release rate.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The addition of magnesium oxide significantly reduces the cracking probability of weld metal while maintaining improved liquid metal wetting and bead appearance, even at high welding travel speeds.

Implementation Method 1

A sulfur source may be added to the flux of steel wire electrodes (such as flux core wire electrodes). Steel wire electrodes containing relatively high amounts of a sulfur source (e.g., approximately 0.01 to 0.1 wt. % of a sulfur source by weight of the electrode) in the flux tend to demonstrate dramatically improved liquid metal wetting properties

Methodology Applied
Scientific EffectSulfur source addition:

Implementation Method 2

The granular powder flux fill core comprises, by weight of the electrode, 0.5 to 4.0 wt. % magnesium oxide (for example, 2.0 to 3.0 wt. % magnesium oxide, or 2.5 wt. % magnesium oxide) and 0.01 to 0.1 wt. % of a sulfur source

Methodology Applied
Scientific EffectMagnesium oxide addition:

Implementation Method 3

The improved wetting performance of such a steel wire electrode to a solid surface persists regardless of whether the solid surface is clean

Methodology Applied
Scientific EffectWetting: Wetting

Data Source

PatentEP3666452A1Improved crack-resistant wire electrode containing added sulfur source and magnesium oxide
Publication Date: 2020.06.17 HOBART BROTHERS LLC
  • EP3666452A1 patent drawingFigure 1~2
  • EP3666452A1 patent drawingFigure 3~4
  • EP3666452A1 patent drawing

AI summary

A tubular welding electrode for arc welding that has improved crack resistance comprises a steel sheath disposed around a granular powder flux fill core. The granular powder flux fill core comprises magnesium oxide and a sulfur source such as iron sulfide.