Gas-Shielded Arc Welding Wire Composition for Adherent Slag Control

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Solution Overview

Problem

Current gas-shielded arc welding wires face issues with spatter generation, coating defects, and corrosion due to slag separation, requiring additional steps for slag removal and inadequate corrosion resistance, especially in underbody parts of vehicles where weight reduction and environmental protection are critical.

Innovation Solution

A wire composition with specific ranges of Mn, Ti, O, C, Si, Cu, S, Al, and P, along with a calculated Ti-to-O ratio, is used to minimize spatter, ensure excellent electrodeposition coatability, and form a thin, adherent slag that prevents coating defects and corrosion, eliminating the need for post-weld slag removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the electrodeposition coating film thickness is increased to prevent corrosion, then corrosion resistance is improved, but the coating film separates during driving and causes coating defects

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidcoating film integrity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The invention changes the chemical composition parameters of the welding wire by precisely controlling the contents of Mn (1.70-3.00 mass%), Ti (0.05-0.50 mass%), and their ratio (0.03 ≤ [Ti]/([Mn]×0.01) ≤ 0.20), which fundamentally alters the slag properties to achieve both thick coating formation and coating adhesion during driving

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite slag structure through the synergistic interaction of Mn and Ti oxides, where MnO provides basicity and TiO2 enhances adhesion, forming a composite slag film that combines both corrosion protection and mechanical adhesion properties

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If physical slag removal is implemented after welding, then coating defects are prevented, but the number of production steps and production cost increase

Engineering Contradiction:
Improvecoating film qualityVSAvoidnumber of production steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention makes the slag self-adherent by optimizing its chemical composition, allowing the slag to naturally bond to the coating film without requiring external removal operations. The controlled Mn-Ti ratio creates a slag that serves its own adhesion function, eliminating the need for additional processing steps

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

By changing the chemical parameters of the slag through controlled wire composition, the invention transforms the slag from a removable byproduct into an integral part of the protective coating system, eliminating the need for post-welding removal operations

Inventive Principle:
Principle #35Parameter changes

3Reliability

If zinc is used for corrosion protection in underbody parts, then corrosion resistance is improved, but zinc evaporates during arc welding and loses protective effect

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidzinc evaporation
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The invention changes the protective mechanism from thermal (zinc sacrificial protection) to chemical (slag film barrier protection). By controlling the Mn-Ti ratio in the slag, a stable, high-melting-point protective film is formed that resists evaporation and provides corrosion protection through physical barrier rather than sacrificial oxidation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the short-lived zinc protection (which evaporates during welding) with a stable slag film that persists through the welding process and provides long-term corrosion protection. The slag, though consumable during welding, creates a durable protective structure

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

4Ease of operation

If spatter is reduced for better workability, then welding quality is improved, but this requires precise control of multiple alloying elements

Engineering Contradiction:
Improvewelding workabilityVSAvoidalloying element control
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The invention identifies and controls the critical parameters of Mn content (1.70-3.00 mass%), Ti content (0.05-0.50 mass%), and their ratio (0.03 ≤ [Ti]/([Mn]×0.01) ≤ 0.20). By focusing on these specific parameter ranges, the invention achieves spatter reduction and improved bead shape without requiring complex control of all alloying elements

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses the composite effect of Mn and Ti in specific proportions to achieve spatter reduction. The synergistic interaction between MnO and TiO2 in the slag creates a stable arc and controlled droplet transfer, reducing spatter while simplifying the overall composition control strategy

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The wire achieves reduced spatter, improved bead shape, and enhanced corrosion resistance without requiring slag removal, ensuring reliable and durable welds with excellent electrodeposition coatability and rust prevention.

Implementation Method 1

gas-shielded arc welding

Methodology Applied
Scientific EffectArc welding: Electric Arc

Implementation Method 2

electrodeposition coating following arc welding

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Data Source

PatentEP4368331A1Wire for gas-shielded arc welding
Publication Date: 2024.05.15 KOBE STEEL LTD
  • EP4368331A1 patent drawingFigure 1~2
  • EP4368331A1 patent drawing
  • EP4368331A1 patent drawing

AI summary

A wire for gas-shielded arc welding contains, in mass% based on a total mass of the wire, Mn: 1.88% or more and 2.70% or less, Ti: 0.10% or more and 0.40% or less, O: more than 0.0050% and 0.0105% or less, C: 0.01% or more and 0.10% or less, Si: 0.05% or more and 0.50% or less, Cu: 0.01% or more and 0.30% or less, S: 0.001% or more and 0.020% or less, Al: 0.10% or less, P: 0.025% or less; and the remainder being Fe and inevitable impurities. The value calculated from formula (1): 1000 × [Ti] × [O]/([Ti] + 50 × [0]) is 2.13 or more and 4.30 or less, where [Ti] represents a Ti content in mass% and [O] represents an O content in mass%.