Wet-Dry Bilayer Resist for Self-Aligned EUV Patterning

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Solution Overview

Problem

Conventional lithographic techniques face challenges in achieving accurate and reliable patterning, particularly with extreme ultraviolet (EUV) lithography, due to issues like image fidelity, line end variability, and the limitations of single-species photoresist films.

Innovation Solution

The use of a multilayer photoresist stack comprising a dry resist film deposited by vapor deposition and a wet resist film deposited by spin-on deposition, where the wet resist film is sensitive to EUV or UV radiation, enabling accurate and reliable EUV lithography by forming a self-aligned cut process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single-species photoresist film is used for EUV lithography, then the process is simple, but image fidelity and line end accuracy deteriorate due to fuzzy ends and variability

Engineering Contradiction:
Improvephotoresist structureVSAvoidline end accuracy
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent divides the photoresist system into two separate layers: a wet photoresist layer deposited by spin-on deposition and a dry photoresist layer deposited by vapor deposition. This segmentation allows each layer to perform specific functions - the wet layer provides good imaging and the dry layer provides sharp line ends - thereby resolving the contradiction between structural simplicity and manufacturing precision

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs a composite photoresist structure combining two different photoresist materials with distinct properties. The wet photoresist and dry photoresist are layered together to create a composite system that leverages the advantages of both materials, achieving high image fidelity while eliminating fuzzy line ends, thus resolving the contradiction between device complexity and manufacturing precision

Inventive Principle:
Principle #40Composite materials

2Device complexity

If conventional single-layer photoresist is used, then the process is straightforward, but image fidelity deteriorates due to radiation sensitivity limitations

Engineering Contradiction:
Improvephotoresist structureVSAvoidimage fidelity
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent segments the photoresist into two functional layers with different radiation sensitivities. The wet photoresist layer is optimized for UV or extreme UV exposure providing high image fidelity, while the dry photoresist layer provides additional radiation sensitivity enhancement. This segmentation resolves the contradiction by allowing each layer to contribute to image fidelity without requiring a single complex material

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The composite photoresist structure combines two photoresist materials that respond differently to radiation. This composite approach enhances overall image fidelity by leveraging the radiation sensitivity characteristics of both materials, resolving the contradiction between maintaining simple processing and achieving high manufacturing precision

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If a multilayer photoresist stack with wet and dry layers is used, then patterning accuracy improves, but process complexity increases

Engineering Contradiction:
Improvepatterning accuracyVSAvoidphotoresist structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent uses segmentation to divide the photoresist into two distinct layers deposited by different methods (spin-on and vapor deposition). This segmentation enables independent optimization of each layer for specific patterning functions, achieving high patterning accuracy while managing complexity through modular layer design

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent transitions from a single-layer to a multilayer photoresist structure, adding a vertical dimension to the photoresist system. This dimensional change allows for enhanced patterning accuracy through the combined effects of multiple layers, while the systematic approach to layer integration keeps the process complexity manageable

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the accuracy and reliability of EUV patterning by truncating fuzzy ends and achieving self-aligned cuts, thereby improving the fidelity and precision of microfabrication processes.

Implementation Method 1

a first layer of a wet photoresist deposited by spin-on deposition... sensitive to EUV or UV radiation

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Implementation Method 2

a second layer of a dry photoresist deposited by vapor deposition

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentUS12249508B2Selective patterning with wet-dry bilayer resist
Publication Date: 2025.03.11 TOKYO ELECTRON LTD
  • US12249508B2 patent drawing
  • US12249508B2 patent drawing
  • US12249508B2 patent drawing

AI summary

A method of patterning a substrate includes forming a multilayer photoresist stack on a substrate. The multilayer photoresist stack includes a first layer of a wet photoresist deposited by spin-on deposition, and a second layer of a dry photoresist deposited by vapor deposition. The first layer is positioned over the second layer. A first relief pattern is formed in the first layer by exposure to a first pattern of actinic radiation of a first wavelength and development of developable portions of the first layer using a first development process. The first relief pattern uncovers portions of the second layer. A multi-color layer of the first relief pattern is formed. The multi-color layer includes the wet photoresist and a third material that is different from the wet photoresist and the dry photoresist. A selective patterning process is executed for uncovered portions of one or two of the wet photoresist, the dry photoresist and the third material.