Wet Industrial Sludge Pavement Slabs with Deflocculant and Water Repellents

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Solution Overview

Problem

Existing methods for manufacturing slabs using recycled construction waste and silicate rock-based industrial sludge face challenges in maintaining mechanical and aesthetic properties due to the small particle size of the sludge, which alters the rheology and granulometric distribution, and require high water content for hydration, leading to inadequate mechanical strength and increased porosity.

Innovation Solution

Incorporating wet industrial sludge with a deflocculant and a water-repellent additive into the slab composition, along with a higher water-cement ratio, to improve mixing and reduce water absorption, while using recycled aggregates and natural aggregates to enhance mechanical strength and reduce water absorption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If wet industrial sludge with small particle size is incorporated into slab composition, then the environmental sustainability is improved by recycling waste material, but the rheology and granulometric distribution are altered leading to inadequate mechanical strength

Engineering Contradiction:
Improveenvironmental sustainabilityVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the water-cement ratio parameter to a higher range (0.6-0.8) than conventional standards, which compensates for the rheological alterations caused by incorporating fine sludge particles. This parameter modification allows the mixture to maintain adequate workability and achieve sufficient mechanical strength (fck ≥ 25 MPa) despite the presence of recycled wet industrial sludge with small particle size

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system combining wet industrial sludge, cement, water, and optional additives (superplasticizers, water-repellent agents). This composite approach allows the fine sludge particles to be effectively integrated with the cement matrix, transforming what would be a weakness (altered rheology) into a workable composite system that meets both environmental and mechanical performance requirements

Inventive Principle:
Principle #40Composite materials

2Ease of operation

If higher water content is used for hydration of the mixture, then the workability is improved, but the porosity increases leading to reduced mechanical strength

Engineering Contradiction:
ImproveworkabilityVSAvoidmechanical strength
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent modifies the water-cement ratio parameter to a controlled higher range (0.6-0.8) that provides adequate workability for incorporating fine sludge particles while being optimized to minimize excessive porosity. This precise parameter control allows the mixture to be properly compacted and achieve the required mechanical strength (fck ≥ 25 MPa) without the negative effects of excessive water content

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces superplasticizers as intermediary chemicals that allow the mixture to achieve adequate workability with optimized water content. These additives improve the flow and compaction characteristics of the sludge-cement mixture without requiring excessive water, thereby preventing the formation of excessive capillary pores that would weaken the final product

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of repair

If wet industrial sludge is incorporated into the slab, then the recycling of industrial waste is improved, but the water absorption increases favouring deterioration

Engineering Contradiction:
Improverecycling efficiencyVSAvoidwater absorption
Core Design Contradiction:
Ease of repairVSObject-affected harmful factors

Solution Approach 1:

The patent introduces water-repellent additives (such as oleic acid or stearic acid) as intermediary substances that modify the surface properties of the sludge-cement matrix. These additives reduce the capillary action and hydrophilicity of the material, thereby decreasing water absorption and preventing deterioration from freezing-thawing cycles and biological growth, while maintaining the recycling benefit

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent modifies the chemical composition parameters by incorporating water-repellent agents at controlled dosages (e.g., 0.5-5% by weight of cement). This parameter change alters the surface energy and hydrophobicity of the slab material, reducing water absorption and improving durability against environmental deterioration while preserving the environmental benefit of waste recycling

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves slabs with improved mechanical bending strength, reduced water absorption, and enhanced resistance to abrasion, freeze-thaw cycles, and bacterial growth, meeting regulatory standards for outdoor and indoor use.

Implementation Method 1

Incorporating wet industrial sludge with a deflocculant and a water-repellent additive into the slab composition

Methodology Applied
Scientific EffectDeflocculation: Flocculation

Implementation Method 2

Incorporating wet industrial sludge with a deflocculant and a water-repellent additive into the slab composition, along with a higher water-cement ratio, to improve mixing and reduce water absorption

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 3

hydraulic cement. A hydraulic cement is a powdery material that, when mixed with water forms a paste that hardens slowly

Methodology Applied
Scientific EffectHydration: Mineral Hydration

Data Source

PatentEP4610241A1Use of an aggregate-based wet industrial sludge for the manufacture of a pavement slab and slab obtained
Publication Date: 2025.09.03 AQUAMBIENTE SERVICIOS PARA EL SECTOR DEL AGUA SAU
  • EP4610241A1 patent drawingFigure 1
  • EP4610241A1 patent drawing
  • EP4610241A1 patent drawing

AI summary

The present invention relates to a use of a wet industrial sludge when additivated with deflocculant for the manufacture of a slab obtainable by moulding with cement as a binder, comprising the composition of the sludge, on a dry basis and by weight, at least 65%, preferably at least 80% and more preferably at least 85% silicate rocks, with an average size less than 0.1 mm; and at least 6.5%, preferably at least 9% resin. The concrete slab obtained comprises at least one layer that, by weight, comprises 20% to 40% of wet industrial sludge, aggregate, cement and at least one water-repellent additive.