Wet-Strength Absorbent Sheet via Intermediary Resin

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Solution Overview

Problem

Existing high-performance wiper products made from mixtures of pulp-derived papermaking fibers and synthetic fibers lack strength, especially wet strength, due to poor interfiber bonding, and are difficult and expensive to produce on conventional papermachines.

Innovation Solution

A wet-laid absorbent sheet comprising a mixture of pulp-derived papermaking fibers and synthetic polymer fibers, incorporating an epihalohydrin/amine functional wet-strength resin, carboxymethylcellulose, and an anionic olefin copolymer resin to enhance wet strength and wet/dry tensile ratios, allowing for economic production on conventional equipment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a mixture of pulp-derived papermaking fibers and synthetic fibers is used to make high-performance wipers, then the wipers can be produced on conventional papermachines, but the wet strength is poor due to poor interfiber bonding

Engineering Contradiction:
Improveproduction on conventional papermachinesVSAvoidwet strength
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent introduces a wet-strength resin as an intermediary substance that bonds between pulp-derived papermaking fibers and synthetic fibers. This resin acts as a mediator that facilitates interfiber bonding despite the inherent incompatibility between different fiber types, thereby improving wet strength while maintaining producibility on conventional equipment

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite material system combining pulp-derived papermaking fibers, synthetic fibers, and wet-strength resin. This composite approach leverages the advantages of both natural and synthetic fibers while using the resin matrix to ensure strong interfiber bonding, resolving the strength deficit of fiber mixtures

Inventive Principle:
Principle #40Composite materials

2Reliability

If microfibers with diameter less than 20 microns are used to improve wiper performance, then cleaning efficiency is enhanced, but production complexity and cost increase

Engineering Contradiction:
Improvecleaning performanceVSAvoidproduction process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent employs conventional papermaking fibers and standard synthetic fibers that can be produced through existing, well-established processes rather than requiring complex microfiber production infrastructure. This approach achieves acceptable performance through material selection and chemical bonding rather than relying on expensive, complex microfiber manufacturing

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the chemical parameters of the fiber mixture by introducing wet-strength resin and other chemicals that modify the bonding characteristics. This chemical parameter change enables strong interfiber bonding without requiring physical parameter changes such as reducing fiber diameter to microfiber levels

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sheet exhibits surprising wet strength and elevated wet/dry tensile ratios, overcoming the production challenges and strength limitations of previous products while being economically viable on conventional papermachines.

Implementation Method 1

an anionic olefin copolymer resin effective to increase the wet/dry tensile ratio of the sheet

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 2

anionic olefin copolymer resin

Methodology Applied
Scientific EffectElectrostatic interaction:

Implementation Method 3

epihalohydrin/amine functional wet-strength resin

Methodology Applied
Scientific EffectChemical crosslinking: Chemical Bonding

Implementation Method 4

a strength agent selected from carboxymethylcellulose and anionic starch

Methodology Applied
Scientific EffectHydrogen bonding:

Data Source

PatentUS8066849B2Absorbent sheet prepared with papermaking fiber and synthetic fiber exhibiting improved wet strength
Publication Date: 2011.11.29 GPCP IP HOLDINGS LLC
  • US8066849B2 patent drawing
  • US8066849B2 patent drawing
  • US8066849B2 patent drawing

AI summary

A wet-laid absorbent sheet includes a mixture of pulp-derived papermaking fibers and synthetic polymer fibers, a strength agent selected from carboxymethylcellulose and anionic starch as well as an epihalohydrin/amine functional wet strength resin. Also included is an anionic olefin copolymer resin effective to increase the wet/dry tensile ratio of the sheet.