Wet-Trapping Ink Layers for Reduced Photoinitiator Residue

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Solution Overview

Problem

Current methods for printing multiple layers of inks and coatings on substrates require high levels of photoinitiators, which can lead to residue issues, contamination, and increased costs, while existing self-initiating systems fail to achieve necessary resistance properties.

Innovation Solution

A wet-trapping method where radiation-curable ink or coating layers containing photoinitiators are applied alongside layers without photoinitiators, allowing for simultaneous curing at the end of the print run, leveraging free radicals generated in adjacent layers to cure intermediate layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If high levels of photoinitiators are used in each ink layer, then complete curing of each layer is achieved, but residue contamination and cost increase

Engineering Contradiction:
Improvecuring completenessVSAvoidphotoinitiator residue
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent extracts the photoinitiator from intermediate ink layers, removing the harmful component while maintaining curing functionality through a single photoinitiator-containing layer combined with electron beam energy

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the curing parameter from UV light activation to electron beam activation, allowing curing without photoinitiators in intermediate layers. This parameter change enables the same curing function with reduced harmful residues

Inventive Principle:
Principle #35Parameter changes

2Reliability

If multiple UV lamps are used to cure each layer, then complete curing is achieved, but energy consumption and equipment complexity increase

Engineering Contradiction:
Improvecuring completenessVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent merges multiple curing operations into a single electron beam curing step that cures all ink layers simultaneously, eliminating the need for multiple UV lamps and reducing energy consumption

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent replaces the mechanical UV lamp system with an electron beam system, achieving curing through electron beam energy rather than electromagnetic radiation, which reduces the number of energy sources required

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Object-generated harmful factors

If photoinitiator-free inks are used, then residue is minimized, but curing capability is lost

Engineering Contradiction:
Improveresidue contaminationVSAvoidcuring capability
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent introduces electron beam energy as an intermediary that enables curing of photoinitiator-free inks. The electron beam acts as a mediator that provides the activation energy needed for curing without requiring photoinitiator chemicals

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the activation parameter from photoinitiator-based UV curing to electron beam-based curing, enabling photoinitiator-free inks to achieve complete curing through alternative energy activation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces the overall photoinitiator load, minimizes residue, enhances solvent resistance, and allows for a more efficient curing process, particularly for difficult-to-cure colors like white and black, while also reducing the number of UV lamps needed.

Implementation Method 1

radiation-curable ink or coating layers (A) containing one or more photoinitiators... curing all coating and/or ink layers simultaneously at the end of the print run

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

leveraging free radicals generated in adjacent layers to cure intermediate layers

Methodology Applied
Scientific EffectFree radical diffusion: Diffusion

Data Source

PatentEP3592473B1Wet-trapping method
Publication Date: 2024.08.14 SUN CHEMICAL CORP

AI summary

The present invention provides a method for applying multiple ink and/or coating layers on a substrate. At least one of the ink and/or coating layers contains one or more photoinitiators, and at least one of the ink and/or coating layers does not contain any photoinitiators. In certain embodiments, all of the ink and/or coating layers are wet trapped and the entire print construct is cured by exposure to UV radiation after all of the ink and/or coating layers have been applied. In certain embodiments, the wet trapping method of the present invention can be used to prepare laminates.