Wetness Indicator Composition Using Leuco Dyes in Hot-Melt Adhesive

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Solution Overview

Problem

Current wetness indicators for hygienic and food packaging applications often start in a colorful state, which may not be preferred by consumers, and lack versatility in final wet colors and adhesion strength on various substrates, with existing manufacturing processes being inefficient and using potentially harmful solvents.

Innovation Solution

A wetness indicator composition comprising a hot-melt adhesive matrix with leuco dyes and color developers that change color from colorless to colorful upon contact with water, offering strong adhesion, storage stability, and absence of flammable or toxic solvents, suitable for a wide range of substrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional colorants are used in wetness indicators, then the indicator shows a colorful state in the initial dry state, but this is not preferred by consumers who associate colorless/white with hygiene and cleanliness

Engineering Contradiction:
Improveconsumer acceptanceVSAvoidinitial color appearance
Core Design Contradiction:
Ease of manufactureVSIllumination intensity

Solution Approach 1:

The patent changes the chemical state of the dye molecule through the use of leuco dyes that exist in a colorless reduced form in the dry state and transform to a colored oxidized form upon contact with water or body fluids, thereby changing the optical parameter from colored to colorless while maintaining manufacturing simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the traditionally harmful characteristic of yellow colorants (poor consumer perception) into a benefit by using leuco dyes that appear colorless in the dry state, leveraging the consumer association of colorless with hygiene and cleanliness, while still providing visible color change functionality when wet

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Strength

If wetness indicators are made with strong adhesion to various substrates, then the indicator remains stable on different surfaces, but existing processes lack versatility and efficiency

Engineering Contradiction:
Improveadhesion strengthVSAvoidmanufacturing process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The hot-melt adhesive matrix serves multiple functions simultaneously: it provides strong adhesion to various substrates, acts as a carrier for the leuco dye and color developer, enables easy application through heat activation, and ensures uniform distribution of indicator components, thereby achieving versatility without increasing process complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent creates a composite material system combining hot-melt adhesive with leuco dye and color developer particles, where the adhesive matrix embeds and protects the indicator components while providing bonding functionality, resulting in a multi-functional material that simplifies the overall manufacturing process

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If conventional solvents are used in wetness indicator formulations, then the colorants can be applied easily, but the solvents are flammable and toxic

Engineering Contradiction:
Improveapplication easeVSAvoidsolvent safety
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes the harmful solvent component from the traditional wetness indicator formulation, replacing it with a solvent-free hot-melt adhesive system that maintains ease of application through thermal activation while eliminating fire and toxicity hazards

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the chemical mechanism of solvent-based application with a thermal mechanism, where heat melts the hot-melt adhesive to enable application and then allows it to solidify, substituting a potentially harmful chemical system with a safer physical process

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Adaptability or versatility

If wetness indicators provide multiple final wet color options, then the versatility for different applications is improved, but the formulation complexity increases

Engineering Contradiction:
Improvecolor varietyVSAvoidformulation complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent enables different local color outcomes by selecting specific leuco dye and color developer combinations tailored to each application's needs, allowing customization of the color change characteristics (e.g., colorless to blue, colorless to green) without complicating the overall formulation approach, as each combination follows the same basic mechanism

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition provides a colorless dry state that changes to a strong, bright color upon wetting, ensuring improved adhesion and storage stability without using harmful solvents, enhancing manufacturing efficiency and consumer preference.

Implementation Method 1

leuco dyes... Upon contact with water or with water-containing fluids, said wetness indicator compositions change their color from one colorless state to a colorful state

Methodology Applied
Scientific EffectLeuco dye color change: Photochromism

Implementation Method 2

comprising a hot-melt adhesive... offering strong adhesion... suitable for a wide range of substrates

Methodology Applied
Scientific EffectAdhesive bonding: Adhesive

Data Source

PatentUS10953129B2Wetness indicator compositions comprising leuco dyes
Publication Date: 2021.03.23 SAVARE I C SRL
  • US10953129B2 patent drawing

AI summary

The present invention relates to wetness indicator compositions that comprise at least one leuco dye and one color developer in a hot-melt adhesive matrix. Upon contact with water or with water-containing fluids, said wetness indicator compositions are apt to change their color from a colorless state to a colorful state or from a first colored state to a second colored state having a color different from the first one; in particular, from a first colorless, white, or translucent state to a second state having a visible color, or vice versa. The disclosed wetness indicator compositions can be used as wetness/fluid indicators in various applications, e.g. in packaging articles and in absorbent articles; in an absorbent mat or sheet or operatory cloth for medical use; in a wound dressing product; in an absorbent mat or sheet for food products.