White Bronze PCB Coating Without Nickel or Palladium

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Solution Overview

Problem

Existing printed circuits for smart cards and medical devices face challenges with the use of palladium and nickel, which are expensive and pose issues in radiofrequency applications and medical settings due to magnetic properties and potential skin contact.

Innovation Solution

A process for depositing a white bronze alloy on printed circuits, which replaces palladium and nickel layers, offering improved cost-effectiveness and suitability for radiofrequency and medical applications, while maintaining electrical and mechanical properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a layer of gold or silver or palladium is deposited on the contacts to obtain a gold finish or silver finish, then the color matching and corrosion resistance are improved, but the manufacturing cost increases and magnetic properties are introduced that are problematic for radiofrequency applications

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive precious metals (gold, silver, palladium) with a cheaper bronze alloy composition. The bronze layer provides sufficient corrosion resistance and color matching without requiring the expensive materials traditionally used for these finishes, directly addressing the cost issue while maintaining protective functionality.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent modifies the alloy composition parameters by using a specific bronze formulation (copper-tin-zinc alloy with controlled ratios) instead of traditional precious metals. This parameter change allows achieving the desired color match and corrosion resistance without introducing magnetic properties, solving both the cost and radiofrequency compatibility issues.

Inventive Principle:
Principle #35Parameter changes

2Strength

If nickel is deposited as an underlying layer for gold to provide structural support, then the mechanical strength is improved, but magnetic properties are introduced that are problematic for radiofrequency applications and medical applications

Engineering Contradiction:
Improvemechanical strengthVSAvoidmagnetic properties
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent removes nickel from the contact layer structure entirely, extracting the harmful magnetic component while maintaining the necessary structural support function through alternative means. The bronze alloy itself provides sufficient mechanical properties without requiring a nickel underlayer, thus eliminating the magnetic property issue for radiofrequency and medical applications.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent uses a composite bronze alloy (copper-tin-zinc) that combines the benefits of multiple metals in a single non-magnetic layer. This composite material provides both the mechanical strength traditionally requiring nickel and the corrosion resistance and color matching, all without magnetic properties that would interfere with radiofrequency or medical applications.

Inventive Principle:
Principle #40Composite materials

3Reliability

If palladium is used to obtain a silver finish, then the color matching and corrosion resistance are improved, but the manufacturing cost increases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive palladium with a cheaper bronze alloy that achieves the same functional outcomes. The bronze layer provides sufficient corrosion resistance and silver-like appearance without the high material cost of palladium, directly reducing manufacturing expenses while maintaining protective and aesthetic properties.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The bronze alloy layer provides economical and effective alternatives to palladium and nickel, enhancing the durability and performance of printed circuits in smart cards and medical devices, particularly in terms of radiofrequency compatibility and medical safety.

Implementation Method 1

at least one operation of electrolytic deposition of at least one layer of at least one second electrically conductive material on at least one area of the first sheet

Methodology Applied
Scientific EffectElectrolytic deposition: Electrodeposition

Data Source

PatentEP4263920B1Method for depositing a bronze alloy on a printed circuit and printed circuit obtained by said method
Publication Date: 2025.04.16 LINXENS HOLDING SAS
  • EP4263920B1 patent drawingFigure 1~3
  • EP4263920B1 patent drawingFigure 4~5
  • EP4263920B1 patent drawingFigure 6~7

AI summary

Disclosed is a method for depositing a bronze alloy on a printed circuit (5). Said method comprises an operation of electrolytically depositing at least one layer of bronze (12) on a copper sheet (10). The bronze layer (12) comprises, after deposition, 45-65% by weight of copper, 35-45% by weight of tin and 2-11% by weight of zinc. Also disclosed is a printed circuit (5) obtained by this method.