White Ink Coating via Controlled Precipitation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing electrostatic printing inks for non-white substrates face challenges in achieving consistent white appearance and high opacity due to high conductivity and background levels, which are not adequately addressed by increasing pigment loading.

Innovation Solution

A method involving heating a polymer resin in a carrier fluid to dissolve it, suspending white pigment particles, and cooling at a controlled rate to precipitate the resin and form a coating on the particles, resulting in a white liquid electrophotographic ink composition with reduced particle conductivity and increased opacity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If pigment loading is increased to improve opacity, then opacity is improved, but conductivity increases and background levels worsen

Engineering Contradiction:
ImproveopacityVSAvoidbackground levels
Core Design Contradiction:
Illumination intensityVSObject-generated harmful factors

Solution Approach 1:

A polymer coating shell is formed around each pigment particle through controlled precipitation, creating a flexible protective layer that reduces conductivity and suppresses background levels while maintaining the pigment's opacity-enhancing properties

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The polymer precipitation process uses controlled cooling rates (0.1-5°C per minute) to optimize the coating formation parameters, achieving the right balance between opacity, conductivity, and background level suppression

Inventive Principle:
Principle #35Parameter changes

2Productivity

If polymer resin is dissolved and precipitated rapidly to increase productivity, then productivity is improved, but manufacturing precision deteriorates

Engineering Contradiction:
Improveproduction speedVSAvoidcoating uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The precipitation process uses dynamic temperature control with a controlled cooling rate range (0.1-5°C per minute), allowing the system to adapt between slow precise coating formation and faster production cycles based on requirements

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

By controlling the cooling rate parameter within a specific range, the process optimizes the balance between precipitation speed and coating quality, ensuring uniform polymer distribution on pigment particles while maintaining productive throughput

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively encapsulates white pigment particles, reducing particle conductivity and background levels while enhancing opacity, leading to a more efficient and less energy-intensive production process with improved printing results.

Implementation Method 1

heating a polymer resin in a carrier fluid to dissolve it

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 2

cooling the carrier fluid at a rate of 2 °C/hr or less to effect precipitation of the polymer resin from the carrier fluid

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 3

cooling the carrier fluid at a rate of 2 °C/hr or less to effect precipitation of the polymer resin from the carrier fluid

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Data Source

PatentEP3174942B1Liquid electrophotographic ink composition
Publication Date: 2020.07.15 HP INDIGO BV
  • EP3174942B1 patent drawingFigure 1

AI summary

A method for coating pigment particles is provided, the method comprising heating a polymer resin in a carrier fluid to dissolve the polymer resin; suspending in the carrier fluid white pigment particles to be coated; and cooling the carrier fluid at a rate of 2 °C/hr or less to effect precipitation of the polymer resin from the carrier fluid such that a coating of the resin is formed on the pigment particles, thereby producing the white liquid electrophotographic ink composition.