White-Light Asphaltene Polymer Composites for Self-Illuminating Pavements

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Solution Overview

Problem

Asphaltene aggregation in road pavements leads to reduced light emission, hindering their use as a self-illuminating material due to aggregation-caused quenching (ACQ), which limits their optical applications.

Innovation Solution

A method involving mixing asphaltenes with a polymer in a solvent to form a solution, coating the pavement, and evaporating the solvent, resulting in homogeneously dispersed asphaltenes that emit white light upon irradiation, using a polymer matrix to prevent aggregation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If asphaltenes are used as a binder component in road pavements, then the pavement structure is formed, but aggregation-caused quenching reduces light emission

Engineering Contradiction:
Improvepavement structure stabilityVSAvoidlight emission intensity
Core Design Contradiction:
Stability of the object's compositionVSIllumination intensity

Solution Approach 1:

The patent introduces a polymer matrix as an intermediary substance that disperses asphaltenes and prevents their aggregation. The polymer acts as a mediator between the asphaltene molecules and the pavement matrix, allowing asphaltenes to maintain their light-emitting properties while still contributing to pavement structure. This resolves the contradiction by enabling both structural stability and high light emission intensity through proper spatial separation of asphaltene molecules.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite material system consisting of asphaltenes dispersed in a polymer matrix. This composite structure combines the structural benefits of asphaltenes with the light-emitting properties of dispersed asphaltene molecules, while the polymer provides both structural support and prevention of aggregation. The composite material approach allows simultaneous achievement of pavement stability and enhanced light emission.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If asphaltenes are dispersed homogeneously in a polymer matrix, then light emission is enhanced, but the complexity of the composite material increases

Engineering Contradiction:
Improvewhite light emissionVSAvoidcomposite material structure
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent utilizes parameter changes in the polymer matrix, specifically selecting polymers with appropriate molecular weight, functional groups, and crystallinity parameters to optimize asphaltene dispersion. By adjusting these material parameters, the patent achieves homogeneous dispersion and enhanced light emission while maintaining relatively simple composite structure. The parameter optimization approach allows achieving high illumination intensity without proportionally increasing structural complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enables self-illuminating pavements that absorb sunlight or UV light from vehicles to emit white light, reducing electricity and maintenance costs, while maintaining efficient light emission.

Implementation Method 1

asphaltenes absorb UV light and emit a wide range of visible light that may cover the entire visible spectrum, producing a white color emission

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 2

coating the pavement with the solution and evaporating the solvent to form a coated pavement

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 3

Pi stacking refers to the attractive, noncovalent pi interactions (orbital overlap) between the pi bonds of aromatic rings

Methodology Applied
Scientific EffectPi stacking:

Implementation Method 4

these attractive forces may lead to a phenomenon called aggregation caused quenching (ACQ) which greatly impedes their optical applications

Methodology Applied
Scientific EffectAggregation caused quenching:

Data Source

PatentUS12398271B1White light-emitting asphaltene-based composites for self-illuminating pavements
Publication Date: 2025.08.26 KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
  • US12398271B1 patent drawing
  • US12398271B1 patent drawing
  • US12398271B1 patent drawing

AI summary

A method of illuminating a pavement including mixing asphaltenes and a polymer in a solvent to form a solution. The method further includes coating the pavement with the solution and evaporating the solvent to form a coated pavement, followed by irradiating the coated pavement. Following the irradiation, the asphaltenes emit light, thereby illuminating the pavement. The asphaltenes are homogeneously dispersed in a polymer matrix in the coated pavement. The polymer has a formula (I) as follows,R1 and R2 are each independently an optionally substituted alkyl group with 1 to 20 carbon atoms or an optionally substituted aryl group with 1 to 20 carbon atoms, and n is 2 to 10000.