White OLED Double-Layer Emission Structure

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Solution Overview

Problem

Current white OLED manufacturing methods face challenges in achieving high emission efficiency and long lifespan due to difficulties in forming multiple emission layers and controlling doping concentrations, leading to unstable color output and short device life.

Innovation Solution

A white OLED structure featuring a double-layered emission layer with a blue emission layer and a layer excluding blue, where the latter includes a phosphorescent material and a mixture of hole transporting and electron transporting materials, along with additional layers for improved interlayer interfaces, is developed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If multiple emission layers are used to generate white light, then color coverage is improved, but device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvecolor coverageVSAvoidemission layer structure
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent combines multiple emission functions into a single integrated emission layer by using a host material system that simultaneously supports blue, green, and red phosphorescent dopants. This merging approach achieves full color coverage while simplifying the device structure compared to using separate emission layers for each color.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The host material serves multiple functions simultaneously: it acts as the matrix for phosphorescent dopants, provides charge transport pathways, and enables white light emission through energy transfer to multiple dopant species. This multi-functionality reduces the need for additional specialized layers.

Inventive Principle:
Principle #6Universality (Multi-functionality)

2Illumination intensity

If doping concentration is increased to improve emission intensity, then brightness is improved, but color stability deteriorates

Engineering Contradiction:
Improveemission intensityVSAvoidcolor stability
Core Design Contradiction:
Illumination intensityVSStability of the object's composition

Solution Approach 1:

The patent optimizes the doping concentration parameters to achieve a balance between emission intensity and color stability. By carefully selecting dopant concentrations within specific ranges and using appropriate host-guest ratios, the system maintains stable color output while achieving high brightness through enhanced phosphorescent emission.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The emission layer uses a composite material system combining host material with multiple phosphorescent dopants (blue, green, and red emitters). This composite approach allows the system to achieve high emission intensity through synergistic energy transfer while maintaining color stability through the balanced composition of multiple emitting species.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If simple emission layer structure is used to reduce manufacturing complexity, then ease of manufacture is improved, but emission efficiency deteriorates

Engineering Contradiction:
Improveprocess simplicityVSAvoidemission efficiency
Core Design Contradiction:
Ease of manufactureVSUse of energy by moving object

Solution Approach 1:

The patent employs a composite emission layer containing host material and phosphorescent dopants that work synergistically to achieve high emission efficiency. The composite structure enables effective energy transfer from the host to the dopants, maintaining high efficiency while using a relatively simple single-layer configuration that is easier to manufacture than multi-layer structures.

Inventive Principle:
Principle #40Composite materials

4Ease of manufacture

If doping concentration is not precisely controlled to simplify manufacturing, then ease of manufacture is improved, but product quality deteriorates

Engineering Contradiction:
Improvedoping controlVSAvoiddoping concentration control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent establishes specific parameter ranges for doping concentrations that provide a tolerance window for manufacturing while maintaining product quality. By optimizing the host-guest ratio and dopant concentrations within defined ranges, the system achieves robust performance that is relatively insensitive to small variations in doping levels, facilitating easier manufacturing without sacrificing precision.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances emission efficiency and extends the lifespan of white OLEDs while maintaining stable color output, as demonstrated by improved driving voltage, current density, and half-life performance.

Implementation Method 1

the emission layer excluding blue includes a phosphorescent material and a mixture comprising a hole transporting material and an electron transporting material

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Implementation Method 2

An OLED is a spontaneous emission display that generates light by combining electrons and holes in the emission layer

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS7803469B2White organic light emitting diode and method for manufacturing the same
Publication Date: 2010.09.28 SAMSUNG DISPLAY CO LTD
  • US7803469B2 patent drawing
  • US7803469B2 patent drawing
  • US7803469B2 patent drawing

AI summary

A white organic light emitting diode (OLED) includes an emission layer that includes a blue emission layer and an emission layer excluding blue. The emission layer excluding blue includes a phosphorescent material and a mixture of a hole transporting material and electron transporting material.