Wide-Bandgap Substrate Processing via Catalyst-Assisted Hydrolysis

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Solution Overview

Problem

Existing methods for processing wide-bandgap semiconductor substrates like SiC and GaN face challenges with the use of rare earth elements, abrasive grains, and hazardous chemicals, leading to environmental concerns and limited processing speed and surface quality.

Innovation Solution

A method using a catalytic substance as a processing reference plane in water, promoting direct hydrolysis and oxidation of the substrate surface without abrasive grains or hazardous chemicals, allowing for precise control of processing speed and surface quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If CMP method is used for processing wide-bandgap semiconductor substrates, then processing speed can be improved, but the surface is damaged due to hard diamond abrasive grains

Engineering Contradiction:
Improveprocessing speedVSAvoidsurface quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent replaces the mechanical polishing system (diamond abrasive grains) with a chemical system (catalyst-assisted chemical reaction). The catalyst promotes chemical reactions that remove material from the substrate surface without mechanical contact, thereby eliminating surface damage while maintaining high processing speeds. This is achieved by bringing a catalyst into contact with the substrate surface in a chemical reaction atmosphere, allowing chemical etching to proceed at controlled rates.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fundamental processing parameter from mechanical force to chemical reactivity. By controlling catalyst type, chemical atmosphere composition, temperature, and pressure, the processing speed can be optimized without compromising surface quality. The chemical reaction parameters are tuned to achieve selective removal of material at rates comparable to or exceeding traditional CMP.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If CARE method using hydrogen fluoride solution is used, then processing speed and precision can be improved, but environmental burden and handling difficulty increase

Engineering Contradiction:
Improveprocessing speedVSAvoidenvironmental burden
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent employs catalysts that can be used in controlled amounts and replaced or regenerated relatively easily. Unlike hydrogen fluoride solutions that require complex handling and disposal systems, the catalyst system allows for simpler waste management. The catalyst promotes the chemical reaction efficiently and can be contained or disposed of with much lower environmental impact.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The catalyst acts as an intermediary substance that enables the chemical reaction between the substrate and processing atmosphere without requiring hazardous materials like hydrogen fluoride. The catalyst mediates the reaction by providing active sites for chemical etching, allowing the use of safer processing atmospheres while maintaining high processing speeds and precision.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If CMP method is used, then processing speed can be improved, but rare earth elements and hazardous chemicals are required

Engineering Contradiction:
Improveprocessing speedVSAvoidhazardous chemicals
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces mechanical polishing with catalyst-assisted chemical etching, eliminating the need for hazardous polishing slurries and rare earth element-containing abrasives. The chemical reaction system uses a catalyst to promote selective material removal in a controlled atmosphere, avoiding the environmental and health issues associated with traditional CMP chemicals.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent converts the potential harm of chemical reactions into a benefit by using a catalyst to control and direct the reaction. Instead of uncontrolled chemical etching that could damage the substrate, the catalyst enables precise, selective removal of material at high speeds, transforming chemical reactivity from a potential hazard into a controlled processing advantage.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Manufacturing precision

If CARE method is used, then surface quality can be improved, but processing speed is limited

Engineering Contradiction:
Improvesurface qualityVSAvoidprocessing speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent introduces dynamic control of the chemical reaction process through catalyst management. By controlling catalyst contact time, catalyst activity, and reaction atmosphere conditions, the processing speed can be adjusted without sacrificing surface quality. The system allows for real-time optimization of processing parameters to achieve both high speed and high precision.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The catalyst is prepared and activated before contact with the substrate, creating optimal conditions for high-speed chemical etching. The processing atmosphere is pre-configured with appropriate gases or vapors, and the catalyst surface is conditioned to maximize reaction efficiency. This preliminary preparation enables the subsequent processing step to proceed at high speeds while maintaining excellent surface quality.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves high-quality surface processing with improved compatibility in clean rooms, reduced environmental burden, and increased processing speed, eliminating the need for rare earth elements and hazardous chemicals.

Implementation Method 1

a catalytic substance having a function of promoting direct hydrolysis of the work piece or promoting hydrolysis of an oxide film on the surface of the work piece

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

a catalytic substance having a function of promoting direct hydrolysis of the work piece or promoting hydrolysis of an oxide film on the surface of the work piece

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentEP3142142B1Method for processing wide-bandgap semiconductor substrate
Publication Date: 2023.12.13 TOHO ENG CO LTD
  • EP3142142B1 patent drawingFigure 1
  • EP3142142B1 patent drawingFigure 2
  • EP3142142B1 patent drawingFigure 3

AI summary

There are provided a processing method for a wide-bandgap semiconductor substrate and an apparatus therefor that use no abrasives or no abrasive grains, or no solution having a large environmental burden at all, can process a single crystal, which is SiC, GaN, AlGaN, or AlN, at a variety of processing speed, can obtain a surface of higher quality than the quality of a surface finished by CMP, and also have an excellent compatibility with a clean room. A catalytic substance having a function of promoting the direct hydrolysis of a work piece (5) or promoting the hydrolysis of an oxide film on the surface of the work piece is used as a processing reference plane (3). In the presence of water (1), the work piece is brought into contact with or extremely close to the processing reference plane at a predetermined pressure.