Winterized Additive Composition for Cold Temperature Drilling Fluids

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Solution Overview

Problem

Drilling fluids face challenges in maintaining appropriate low cold temperature rheology while maintaining high viscosity and stability at elevated temperatures, especially in subsea drilling where conventional rheology modifiers solidify or become too viscous in cold environments, affecting their handling and effectiveness.

Innovation Solution

The use of a winterized additive composition combining a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers with a winterizing agent having a branched structure and unsaturation, which enhances low temperature stability without compromising high temperature stability and rheological properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If conventional rheology modifiers are used to maintain high viscosity and stability at elevated temperatures, then high temperature stability is improved, but cold temperature rheology deteriorates (fluids solidify or become too viscous)

Engineering Contradiction:
Improvehigh temperature stabilityVSAvoidcold temperature handling
Core Design Contradiction:
Stability of the object's compositionVSEase of operation

Solution Approach 1:

The invention segments the rheology modification function into two distinct components: a conventional rheology modifier for high temperature stability and a winterizing agent for cold temperature fluidity. This segmentation allows each component to optimize its performance in its respective temperature range without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention creates a composite additive system combining a rheology modifier (such as a polymer) with a winterizing agent (such as a pour point depressant). This composite approach enables the system to exhibit dual functionality: maintaining viscosity at high temperatures while preventing solidification at low temperatures, thereby resolving the contradiction between high temperature stability and cold temperature handling.

Inventive Principle:
Principle #40Composite materials

2Reliability

If rheology modifiers are used to increase viscosity for cuttings suspension, then cuttings suspension capability is improved, but cold temperature flowability deteriorates

Engineering Contradiction:
Improvecuttings suspension capabilityVSAvoidcold temperature flowability
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention separates the functions of viscosity enhancement and cold temperature flowability into two distinct additives: the rheology modifier provides cuttings suspension capability through viscosity enhancement at high temperatures, while the winterizing agent independently provides cold temperature flowability by preventing crystallization and maintaining fluidity at low temperatures.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The winterizing agent changes the physical parameters of the drilling fluid at cold temperatures by depressing the pour point and preventing crystallization of the base oil and additives. This parameter change (lowering pour point) enables the fluid to maintain flowability at temperatures where conventional rheology modifiers would cause solidification.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If conventional additives are used without modification, then formulation simplicity is maintained, but cold temperature performance deteriorates (requiring pre-treatment)

Engineering Contradiction:
Improveformulation simplicityVSAvoidcold temperature performance
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The invention merges the functions of a conventional rheology modifier with a winterizing agent into a single additive composition package. This combination eliminates the need for separate pre-treatment steps while maintaining both high temperature stability and cold temperature performance, thereby improving reliability without significantly increasing formulation complexity.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The winterizing agent performs preliminary action by preventing crystallization and maintaining fluidity at cold temperatures before the drilling operation begins. This preliminary protective action ensures that the drilling fluid is ready for immediate use in cold environments without requiring pre-heating or other pre-treatment procedures.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The additive composition maintains fluidity and rheological stability at cold temperatures, preventing sag and ensuring long-term high temperature stability, allowing for effective use in cold environments without the need for pre-treatment, thus improving drilling efficiency and fluid handling.

Implementation Method 1

a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers

Methodology Applied
Scientific EffectRheology modification:

Implementation Method 2

a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation

Methodology Applied
Scientific EffectWinterizing effect:

Implementation Method 3

maintaining appropriate low cold temperature rheology while maintaining high viscosity and stability at elevated temperatures

Methodology Applied
Scientific EffectTemperature stability:

Data Source

PatentUS11708519B2Additive to improve cold temperature properties in oil-based fluids
Publication Date: 2023.07.25 SCHLUMBERGER TECH CORP
  • US11708519B2 patent drawing
  • US11708519B2 patent drawing
  • US11708519B2 patent drawing

AI summary

An additive composition for improving one or more cold temperature properties in oil-based fluids is provided. One additive composition may include a first additive component selected from at least one alcohol ethoxylate, at least one amine ethoxylate, at least one ethylene oxide/propylene oxide copolymer, or a combination thereof, wherein the first additive component has an HLB ranging from about 4 to about 10. The additive composition may also include a second additive component selected from at least one alcohol, propylene glycol, at least one alcohol ethoxylate, or a combination thereof, wherein the second additive component has a total number of carbons from about 2 to about 30 carbons and a degree of ethoxylation is from zero to about 10.