Multi-Layer Cap Structure for Tungsten Word Line Stress and Etch Protection

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Solution Overview

Problem

Existing flash memory technologies face challenges in forming word lines with stable structures, as cap layers with high etch rates can cause damage and stress issues during anisotropic etching, leading to narrowed word lines and increased resistance, which can result in defective memory chips.

Innovation Solution

A multi-layer cap structure is used, comprising a first layer with a low etch rate for protection and a second layer with opposite stress to balance and negate the stress of the underlying metal layer, such as tungsten, to prevent word line collapse and maintain desired dimensions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a single-layer cap structure with high etch rate is used, then etching speed is improved, but the metal layer is damaged and word line dimensions are narrowed

Engineering Contradiction:
Improveetching speedVSAvoidword line dimension
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The cap structure is segmented into multiple layers: a first cap layer with high etch rate for fast etching, and a second cap layer with low etch rate for protection. This segmentation allows each layer to perform its specific function optimally without compromising the other.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The second cap layer acts as an intermediary protective layer between the etching process and the metal layer. It has low etch rate and provides a barrier that prevents the etching process from directly damaging the metal layer, thus protecting word line dimensions.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Device complexity

If a single-layer cap structure is used, then device complexity is reduced, but stress balance is insufficient leading to word line collapse

Engineering Contradiction:
Improvecap structure complexityVSAvoidword line structural stability
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The cap structure is divided into functional segments: the first cap layer provides stress balance with tensile stress to counteract compressive stress from the metal layer, while the second cap layer provides protection. This segmentation enables both stress management and structural stability.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The cap structure uses composite materials with different properties: the first cap layer material is selected for its stress characteristics (tensile stress) to balance the metal layer's compressive stress, while the second cap layer material is selected for its low etch rate and protective properties. This composite approach achieves both stress balance and structural stability.

Inventive Principle:
Principle #40Composite materials

3Reliability

If a multi-layer cap structure is used, then protection and stress balance are improved, but device complexity increases

Engineering Contradiction:
Improveword line integrityVSAvoidcap structure complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The cap structure is segmented into exactly two functional layers, which is the minimum number needed to achieve both protection and stress balance. This controlled segmentation improves reliability without excessive complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The first cap layer serves multiple functions: it provides stress balance (tensile stress to counteract compressive stress) and also serves as part of the protective cap structure. This multi-functionality reduces the need for additional separate layers, thereby limiting complexity increase.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-layer cap structure effectively protects the metal layer during etching, reduces stress, and maintains the integrity of word lines, preventing collapse and ensuring optimal access times in memory cells.

Implementation Method 1

The multi-layer cap structure may include a layer with a low etch rate to protect metal from damage during anisotropic etching

Methodology Applied
Scientific EffectEtch rate difference:

Implementation Method 2

The multi-layer cap structure may include a layer with a stress (e.g. tensile) that is opposite to the stress of the metal (e.g. compressive) to provide low combined stress

Methodology Applied
Scientific EffectStress compensation:

Data Source

PatentUS9401275B2Word line with multi-layer cap structure
Publication Date: 2016.07.26 SANDISK TECHNOLOGIES LLC
  • US9401275B2 patent drawing
  • US9401275B2 patent drawing
  • US9401275B2 patent drawing

AI summary

Word lines are formed from a stack of layers that includes a metal (e.g. tungsten) layer with an overlying multi-layer cap structure. The multi-layer cap structure includes a layer with a low etch rate to protect metal from damage during anisotropic etching. The multi-layer cap structure includes a layer with stress (e.g. tensile) that is opposite to the stress of the metal (e.g. compressive) to provide low combined stress.