Work Function Metal Undercut Control via Polymer Brush Protection

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Solution Overview

Problem

Conventional lateral etch processes limit the minimum distance between n-type and p-type nanosheet devices in semiconductor manufacturing, restricting device density due to excessive work function metal (WFM) removal requirements.

Innovation Solution

A method involving the formation of a polymer brush layer to prevent lateral removal of WFM portions between nanosheet devices, using an organic planarization layer to protect certain WFM regions and selectively removing WFM layers, allowing for narrower WFM regions and reduced distance between devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional lateral etch processes are used to remove work function metal layers, then WFM layers can be removed, but excessive WFM removal occurs between nanosheet devices requiring compensation and limiting minimum device spacing

Engineering Contradiction:
ImproveWFM removal precisionVSAvoiddevice density
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

A polymer brush layer is introduced as an intermediary protective coating on the work function metal layers between nanosheet devices. This polymer brush layer selectively prevents lateral etch removal of WFM in the regions between devices while allowing complete removal of WFM from the nanosheet device regions, thereby eliminating the need for compensation and enabling tighter device spacing

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The etch protection is applied locally only to specific regions between nanosheet devices through the polymer brush layer. This creates different etch resistance properties in different spatial locations: protected regions between devices versus unprotected regions on devices, achieving precise spatial control over WFM removal

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If extensive over-etching is performed to remove WFM layers between nanosheets, then WFM removal is achieved, but the minimum distance between n-type and p-type nanosheet devices is limited

Engineering Contradiction:
ImproveWFM removal completenessVSAvoiddistance between devices
Core Design Contradiction:
Ease of manufactureVSLength of stationary object

Solution Approach 1:

The polymer brush layer serves as a protective intermediary that enables extensive over-etching to be performed without damaging the WFM layers between devices. The polymer brush remains intact during etching, allowing complete WFM removal from device regions while preserving WFM in inter-device regions, thus reducing the minimum required distance between devices

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If WFM layers are removed to increase device density, then more devices can be packed, but lateral etch causes unwanted WFM removal between devices

Engineering Contradiction:
Improvedevice densityVSAvoidWFM layer integrity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The polymer brush layer acts as a protective intermediary that enables aggressive lateral etching processes to be used for increasing device density. The polymer brush selectively shields WFM layers between devices from etch damage while allowing complete WFM removal from device regions, thereby enabling higher device density without compromising WFM layer integrity

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables narrower WFM regions and reduced distance between nanosheet devices, increasing device density without the need for excessive WFM removal compensation, thereby enhancing semiconductor device packing efficiency.

Implementation Method 1

a polymer brush layer is formed on exposed portions of the work function metal layers and the high-k dielectric layers

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

The polymer brush layer prevents removal of the work function metal portions in between the nanosheet devices

Methodology Applied
Scientific EffectPhysical barrier: Physical Containment

Implementation Method 3

The OPL covers the second nanosheet device and a first part of the work function metal layer in the space between the first and second nanosheet devices

Methodology Applied
Scientific EffectPhysical barrier: Physical Containment

Implementation Method 4

the first plurality of work function metal layers is selectively removed from the first region with respect to the polymer brush layer

Methodology Applied
Scientific EffectChemical etching:

Data Source

PatentUS10374034B1Undercut control in isotropic wet etch processes
Publication Date: 2019.08.06 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US10374034B1 patent drawing
  • US10374034B1 patent drawing
  • US10374034B1 patent drawing

AI summary

A method for manufacturing a semiconductor device includes forming a first nanosheet device and forming a second nanosheet device spaced apart from the first nanosheet device in respective first and second regions corresponding to first and second types. The first and second nanosheet devices respectively include a first and a second plurality of work function metal layers, and a work function metal layer extends from the first and second plurality of work function metal layers in the space between the nanosheet devices. In the method, part of the work function metal layer is removed from the space between the nanosheet devices, and the removed part of the work function metal layer is replaced with a polymer brush layer. The first plurality of work function metal layers is selectively removed from the first region with respect to the polymer brush layer.