Xanthene Compound Light Shielding Long-Wavelength Absorption

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Solution Overview

Problem

Conventional xanthene compounds have insufficient light shielding properties, particularly in the long-wavelength region of visible light due to their maximum absorption wavelength around 550 nm.

Innovation Solution

A xanthene compound represented by Formula (1) with specific structural modifications, including aryl groups with electron donating substituents, is used in a resin composition along with an alkali-soluble resin and a photosensitive compound, which enhances the light shielding properties by extending the maximum absorption wavelength to the long-wavelength region.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If a conventional xanthene compound is used as a colorant in the resin composition, then the resin composition achieves high heat resistance, but the light shielding property particularly in the long-wavelength region of visible light is insufficient

Engineering Contradiction:
Improveheat resistanceVSAvoidlight shielding property
Core Design Contradiction:
TemperatureVSObject-affected harmful factors

Solution Approach 1:

The patent modifies the molecular structure of the xanthene compound by introducing specific substituents (electron-donating groups at positions 2 and 7, and electron-withdrawing groups at positions 4 and 5) to change the absorption characteristics. This structural parameter change extends the maximum absorption wavelength from around 550 nm to 600 nm or more, thereby improving light shielding in the long-wavelength region while preserving the heat resistance inherent to the xanthene core structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite colorant system by combining the modified xanthene compound with specific resins (polyimide, polyamide-imide, or polyester). This composite approach allows the xanthene compound's enhanced absorption properties to work synergistically with the resin matrix, achieving both high heat resistance from the resin and improved light shielding from the modified colorant

Inventive Principle:
Principle #40Composite materials

2Device complexity

If the maximum absorption wavelength of the xanthene compound is around 550 nm, then the compound maintains simplicity in structure, but the light shielding property in the long-wavelength region is insufficient

Engineering Contradiction:
Improvestructural complexityVSAvoidlight shielding property
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The patent systematically modifies the xanthene structure by adding specific substituent groups at defined positions (electron-donating groups at positions 2 and 7, electron-withdrawing groups at positions 4 and 5). These controlled structural parameter changes extend the absorption spectrum to 600 nm or more while maintaining reasonable structural complexity through the use of common aromatic substituents rather than overly complex molecular architectures

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified xanthene compound effectively shields light up to the long-wavelength region of visible light, improving the light shielding properties of the resin composition and enhancing the performance of organic electroluminescence (EL) display devices.

Implementation Method 1

A xanthene compound (b) having a maximum absorption wavelength at 600 nm or more and less than 800 nm at 350 to 800 nm

Methodology Applied
Scientific EffectLight absorption: Absorption (EM radiation)

Data Source

PatentUS20240248396A1Xanthene compound, resin composition, cured object, method for producing cured object, organic el display device, and display device
Publication Date: 2024.07.25 TORAY INDUSTRIES INC
  • US20240248396A1 patent drawing
  • US20240248396A1 patent drawing
  • US20240248396A1 patent drawing

AI summary

An object of the present invention is to provide a xanthene compound having high heat resistance and capable of shielding light up to a long-wavelength region of visible light as compared to a conventional xanthene compound. In order to solve the above problem, a xanthene compound (b) of the present invention is a xanthene compound (b) represented by Formula (1).