Variable Count Time X-Ray Spectral Waveform Analysis

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Solution Overview

Problem

Conventional X-ray spectrum measurement techniques using wavelength-dispersive X-ray spectrometers face challenges in obtaining accurate waveforms in minimum time due to statistical fluctuations, especially near peak tops, and fail to adapt scan speeds according to varying peak heights.

Innovation Solution

The method involves varying the count time at each spectral position to equalize the variation caused by statistical fluctuations to a specified tolerance value, allowing for precise measurement and display of the X-ray spectral waveform starting from background levels, passing through peaks, and returning to background levels in minimal time.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If constant count time per point is used in conventional X-ray spectrum measurement, then the measurement process is simple, but statistical fluctuations cause large variations near peak tops and accurate waveforms cannot be obtained in short-time measurements

Engineering Contradiction:
Improveaccuracy of X-ray spectral waveformVSAvoidmeasurement time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent applies dynamics by making the count time variable rather than constant. The count time is dynamically adjusted based on the measured X-ray intensity at each spectral position, with longer count times allocated to regions with lower intensity (higher statistical fluctuations) and shorter count times to regions with higher intensity. This dynamic adjustment resolves the contradiction by achieving uniform statistical precision across the entire spectrum without requiring uniformly long measurement times.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent changes the parameter of count time from a constant value to a variable value that depends on the local X-ray intensity and desired statistical precision. By calculating and applying different count times for different spectral positions, the system achieves accurate waveform measurement without requiring the entire spectrum to be measured for the maximum necessary time, thus resolving the time-accuracy contradiction.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If the scanning speed is reduced near peaks to minimize statistical fluctuations, then measurement accuracy near peaks improves, but the overall measurement time increases significantly

Engineering Contradiction:
Improveaccuracy near peak topsVSAvoidmeasurement efficiency
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent applies local quality by assigning different count times to different spectral positions based on their specific needs. Rather than uniformly reducing scanning speed across the entire spectrum, the system locally adjusts count time only where necessary (at spectral positions with low X-ray intensity), while maintaining faster scanning at positions with high intensity. This resolves the contradiction by achieving local accuracy improvement without global productivity loss.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent implements partial action by applying extended count times only to the specific spectral regions that require them (areas with high statistical fluctuations), rather than extending count time across the entire spectrum. This selective approach achieves the necessary measurement precision where needed while minimizing the impact on overall measurement efficiency.

Inventive Principle:
Principle #16Partial or excessive action

3Measurement precision

If conventional techniques measure the whole X-ray spectrum for a long time or perform repeated measurements, then comprehensive spectral data is obtained, but the measurement process becomes time-consuming and impractical

Engineering Contradiction:
Improvecompleteness of spectral waveformVSAvoidtotal measurement time
Core Design Contradiction:
Measurement precisionVSLoss of time

Solution Approach 1:

The patent uses dynamic count time allocation to achieve complete spectral waveform measurement in a single pass without requiring repeated measurements. By adaptively adjusting count time at each spectral position based on local statistical requirements, the system obtains comprehensive spectral data in one measurement cycle, resolving the contradiction between completeness and time consumption.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the acquisition of an X-ray spectral waveform with desired accuracy in one measurement and minimal time, allowing for accurate quantitative analysis of elements with high concentration and intense peak characteristics.

Implementation Method 1

The analyzing crystal C having a crystal lattice plane curved with a radius of curvature of 2R always faces the center O of the Rowland circle. The relationship between the wavelength λ of X-rays and the spectral position L can be known from Eq. (3).

Methodology Applied
Scientific EffectX-ray diffraction: Bragg Diffraction

Implementation Method 2

Characteristic X-rays produced from chemical elements constituting a substance have wavelengths intrinsic to the respective elements.

Methodology Applied
Scientific EffectX-ray emission: X-Ray

Data Source

PatentUS7742565B2Method and apparatus for analysis using X-ray spectra
Publication Date: 2010.06.22 JEOL LTD
  • US7742565B2 patent drawing
  • US7742565B2 patent drawing
  • US7742565B2 patent drawing

AI summary

A method for precisely measuring and displaying the whole profile of an X-ray spectral waveform, which rises from a background level and finally returns to the background level after passing across a peak. X-rays are counted for a time interval of to at a spectral position, resulting in X-ray N counts not containing statistical fluctuations. A standard deviation Eo representing a variation accompanying the N counts is given by Sqrt(N). Where the variation is greater than a given magnitude (tolerance error Er for display) at a spectral position where the X-ray intensity is high, X-rays are counted for a time interval of tm longer than the time interval to, producing increased counts Nm.