X-ray Fluorescence Spectrometer Total Analysis Time Calculation

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Solution Overview

Problem

Conventional X-ray fluorescence spectrometers calculate total analysis time based solely on counting time, which can significantly differ from the actual total analysis time, making it difficult to determine a suitable counting time for achieving necessary analytical precision.

Innovation Solution

A sequential X-ray fluorescence spectrometer that includes a total analysis time display unit to calculate and display the total analysis time by accounting for sample transfer time, measurement condition change time, and counting time, allowing for accurate determination of counting time for required analytical precision.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If only counting time is calculated and outputted, then the calculation is simple, but the total analysis time information is inaccurate and misleading

Engineering Contradiction:
Improvesimplicity of time calculationVSAvoidinaccuracy of total analysis time information
Core Design Contradiction:
Ease of operationVSLoss of information

Solution Approach 1:

The patent segments the total analysis time into distinct components: sample transfer time, measurement condition change time, and counting time. Each component is calculated separately and then aggregated to provide the total analysis time, ensuring accuracy while maintaining clarity in the calculation process.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The system provides feedback by displaying both the individual time components and the total analysis time to the user. This allows users to understand the breakdown of time usage and verify the accuracy of the calculation, preventing information loss while maintaining operational simplicity.

Inventive Principle:
Principle #23Feedback

2Productivity

If counting time per component is set short to increase throughput, then productivity increases, but the total analysis time becomes significantly different from total counting time

Engineering Contradiction:
Improvethroughput of sample analysisVSAvoiddiscrepancy between total counting time and total analysis time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent performs preliminary calculation of sample transfer time and measurement condition change time before the actual analysis. By pre-determining these fixed time components, the system can accurately calculate total analysis time even when counting times are shortened to increase throughput, preventing time loss discrepancies.

Inventive Principle:
Principle #10Preliminary action

3Measurement precision

If counting time is extended to improve analytical precision, then measurement precision improves, but total analysis time increases

Engineering Contradiction:
Improveprecision of X-ray intensity measurementVSAvoidtotal analysis time
Core Design Contradiction:
Measurement precisionVSDuration of action of moving object

Solution Approach 1:

The patent allows dynamic adjustment of counting time as a variable parameter while keeping sample transfer time and measurement condition change time as fixed parameters. Users can optimize counting time based on desired precision requirements, and the system automatically recalculates total analysis time to reflect these parameter changes, balancing precision and duration.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables easy determination of total analysis time and appropriate counting time, improving analytical precision and throughput by accurately accounting for all components of the analysis process.

Implementation Method 1

irradiate a sample with primary X-rays to measure an intensity of fluorescent X-rays generated

Methodology Applied
Scientific EffectX-ray fluorescence: Fluorescence

Implementation Method 2

a detector to detect the fluorescent X-rays

Methodology Applied
Scientific EffectX-ray detection: Photoelectric Effect

Data Source

PatentEP4036563B1X-ray fluorescence spectrometer
Publication Date: 2024.03.20 RIGAKU CORP
  • EP4036563B1 patent drawingFigure 1
  • EP4036563B1 patent drawingFigure 2A
  • EP4036563B1 patent drawingFigure 2B

AI summary

A sequential X-ray fluorescence spectrometer according to the present invention includes a total analysis time display unit configured to measure, for each kind of analytical sample, a standard sample which contains a component at a known content as a standard value to determine a measured intensity of each measurement line corresponding to the component. The total analysis time display unit is further configured to calculate, for each component, a counting time which gives a specified analytical precision by using the standard value and the measured intensity and to calculate a total counting time as a sum of the counting times of respective components. The total analysis time display unit is configured to calculate a total analysis time as a sum of the total counting time and a total non-counting time and to output the calculated total analysis time and the calculated counting times of the respective components.