Yb Ag Cathode Structure for OLED Transmittance

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Solution Overview

Problem

Conventional top-emitting OLED display devices face issues with high work function cathodes using transparent conductive materials and high resistance values when using semi-transmissive metal layers, which affect transmittance and emission efficiency.

Innovation Solution

A top-emitting OLED display device with a cathode formed by stacking ytterbium (Yb) and silver (Ag) layers, where Yb is deposited to a thickness of 20-30 Å and Ag to 70-90 Å, optimizing the thickness to achieve a sheet resistance of 45 ohm/square or lower and transmittance of 40% or more over the emission wavelength range.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If the upper electrode is formed of transparent conductive material such as ITO or IZO, then transmittance is improved, but work function is too high for cathode application

Engineering Contradiction:
ImprovetransmittanceVSAvoidwork function suitability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent applies composite materials by combining Yb and Ag in a layered structure. The Yb layer provides low work function (4.5 eV) suitable for electron injection as cathode, while the Ag layer enhances electrical conductivity. This composite structure resolves the contradiction by integrating materials with complementary properties that neither material alone can provide.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If the upper electrode is formed of semi-transmissive metal layer such as MgAg, then transmittance is improved, but resistance value increases

Engineering Contradiction:
ImprovetransmittanceVSAvoidresistance value
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent uses a composite structure of Yb and Ag layers where the Ag layer specifically addresses the resistance issue. Silver has excellent electrical conductivity, and by forming a separate Ag layer (70-90 Å thick) on top of the Yb layer, the patent achieves low resistance while maintaining the low work function property of Yb for electron injection.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent optimizes the thickness parameters of both Yb (20-30 Å) and Ag (70-90 Å) layers to achieve the desired balance between transmittance and resistance. By precisely controlling these thickness parameters, the patent achieves sheet resistance of 45 ohm/square or lower while maintaining transmittance of 40% or more.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If the cathode thickness is increased to reduce resistance, then resistance value is improved, but transmittance decreases

Engineering Contradiction:
Improveresistance valueVSAvoidtransmittance
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent segments the cathode into two distinct functional layers: a Yb layer (20-30 Å) responsible for electron injection due to its low work function, and an Ag layer (70-90 Å) responsible for electrical conductivity. This segmentation allows each layer to be optimized for its specific function without compromising the other, resolving the contradiction between resistance and transmittance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The layered composite structure of Yb and Ag enables the system to achieve both low resistance and high transmittance simultaneously. The total thickness is controlled at 90-120 Å to maintain transmittance of 40% or more, while the Ag layer provides the necessary electrical conductivity with sheet resistance of 45 ohm/square or lower.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The Yb/Ag cathode structure enhances transmittance and emission efficiency, minimizes microcavity effects, and ensures balanced color output when mixing different wavelengths, improving overall light emission characteristics.

Implementation Method 1

a second electrode being a cathode and including an ytterbium (Yb) layer formed on the organic layer and a silver (Ag) formed on the ytterbium layer

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentEP1939954B1Organic light emitting diode display device and method of fabricating the same
Publication Date: 2017.02.15 SAMSUNG DISPLAY CO LTD
  • EP1939954B1 patent drawing
  • EP1939954B1 patent drawing
  • EP1939954B1 patent drawing

AI summary

An organic light emitting diode (OLED) display device includes a substrate (100), a first electrode (110) disposed on the substrate, an organic layer (120) including an emission layer disposed on the first electrode, and a second electrode (130) including stacked layers of Yb and Ag on the organic layer. A method of fabricating the device is disclosed.