Thermistor Sintered Body Phases for Stable B Constant Control

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Solution Overview

Problem

Thermistor sintered bodies produced on an industrial scale often experience composition deviations, leading to unstable B constants, which affect their ability to accurately detect temperature across a wide range.

Innovation Solution

A thermistor sintered body comprising a Y2O3 phase and a YMnO3 or YCrO3 phase, with specific compositions of Cr, Mn, Ca, and Sr, and a balanced inclusion of unavoidable impurities and Y, ensures a stable B constant range of 10-25 K, even with composition deviations.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a thermistor sintered body is produced on an industrial scale, then productivity is improved, but manufacturing precision deteriorates due to composition deviation

Engineering Contradiction:
Improveindustrial production scaleVSAvoidcomposition deviation
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The invention changes the compositional parameters by specifying precise ranges for Cr (3-20 mol%), Mn (5-18 mol%), Ca (1-18 mol%), and Sr (1-25 mol%). By defining these parameter ranges and their interactions, the patent enables industrial production while maintaining stable B constants despite normal composition variations that occur at scale.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite material system containing multiple elements (Cr, Mn, Ca, Sr, Y) in specific combinations. This composite approach allows the material to maintain stable electrical characteristics and B constants even when individual element compositions vary during industrial production, as the multiple components work together to compensate for deviations.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the B constant is stabilized despite composition deviation, then reliability is improved, but device complexity increases due to multiple additive elements

Engineering Contradiction:
ImproveB constant stabilityVSAvoidmultiple additive elements
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention merges multiple additive elements (Cr, Mn, Ca, Sr) into a single integrated material system. Rather than using separate components or layers, all additives are combined within the thermistor sintered body structure, allowing them to work synergistically to stabilize the B constant while maintaining a relatively simple overall device structure.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The multiple additive elements serve multiple functions simultaneously: Cr and Mn control the base resistance and B constant, while Ca and Sr provide compositional buffering that compensates for production variations. This multi-functionality allows a single material composition to achieve both performance targets and production robustness without requiring additional device components.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a thermistor sintered body with a stable B constant, enabling accurate temperature detection despite composition variations, by dissolving Ca and Sr in the YMnO3 or YCrO3 phase, thereby maintaining consistent resistance characteristics.

Implementation Method 1

Ca and Sr are preferably dissolved in the YMnO3 phase or the YCrO3 phase

Methodology Applied
Scientific EffectDissolution: Solvation

Implementation Method 2

The thermistor detects a temperature on the basis of a change in the resistance value

Methodology Applied
Scientific EffectThermistor effect: Thermo-resistive Effect

Data Source

PatentUS12385792B2Thermistor sintered body and temperature sensor element
Publication Date: 2025.08.12 SHIBAURA ELECTRONICS CO LTD
  • US12385792B2 patent drawing
  • US12385792B2 patent drawing
  • US12385792B2 patent drawing

AI summary

Provided is a thermistor sintered body which stably provides a desired B constant even if a composition deviation of an additive element has occurred. The thermistor sintered body-includes a Y2O3 phase and a YMnO3 phase, wherein a chemical composition of Cr, Mn, Ca and Y excluding oxygen includes Cr: 3 mol % or less (while including 0%), Mn: 5 to 18 mol %, Ca: 1 to 18 mol %, and Sr: 1 to 25 mol %, with the balance being unavoidable impurities and Y. In the thermistor sintered body, Ca and Sr may be dissolved in the YMnO3 phase.