Zeolitic Adsorbent Purification of Aromatic Liquids

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Solution Overview

Problem

Aromatic liquid compounds degrade under thermal stresses, leading to the formation of toxic and hazardous byproducts that reduce their useful life and pose safety risks, with existing separation methods being time- and energy-consuming, making them unsuitable for industrial applications.

Innovation Solution

The process involves contacting aromatic liquid compounds with a zeolitic adsorbent material to selectively adsorb and remove degradation products, thereby extending the lifetime of the compounds and preventing environmental toxicity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional separation methods (settling, crystallization, recrystallization) are used to remove degradation products, then purification is achieved, but the process becomes highly time- and energy-consuming

Engineering Contradiction:
Improvepurification effectivenessVSAvoidprocessing time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent employs zeolite crystals with porous structures as adsorbents to remove degradation products. The porous nature of zeolites provides high surface area and selective adsorption capacity, enabling efficient purification without the extensive time required by conventional methods like crystallization and recrystallization.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention changes the approach from thermal/phase-based separation (crystallization, distillation) to adsorption-based separation. By utilizing the adsorption properties of zeolites, the process achieves purification under milder and faster conditions, reducing both time and energy consumption while maintaining effectiveness.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional separation methods are used to remove degradation products, then purification is achieved, but energy consumption becomes excessively high

Engineering Contradiction:
Improvepurification effectivenessVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by stationary object

Solution Approach 1:

Zeolite crystals utilize their porous structure to provide high surface area for adsorption, enabling effective removal of degradation products at lower energy costs compared to thermal separation methods like distillation or crystallization that require significant heating energy.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent replaces energy-intensive mechanical/thermal separation systems (heating for distillation, cooling for crystallization) with an adsorption system that operates at lower energy levels, utilizing the natural adsorption affinity of zeolites for degradation products.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Object-affected harmful factors

If spent aromatic liquid compound is replaced to remove impurities, then safety is improved, but loss of time and yield increases

Engineering Contradiction:
Improvesafety from toxic byproductsVSAvoidyield loss
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The invention extracts and removes degradation products from the spent aromatic liquid compound through adsorption on zeolite crystals, allowing the bulk aromatic liquid to be recovered and reused. This eliminates the need to discard and replace the entire spent compound, thereby preventing yield loss while maintaining safety.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Instead of discarding the spent aromatic liquid compound containing impurities, the process recovers it by removing the degradation products through adsorption. This recovery enables the aromatic liquid to be reused in the same application, maintaining both safety and productivity.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces the amount of degradation products, improving the longevity of aromatic liquid compounds and ensuring safer industrial use by effectively trapping and removing harmful byproducts, thus enhancing operational efficiency and reducing environmental impact.

Implementation Method 1

the trapping being performed by selective adsorption of said degradation products

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

said process comprising at least a step in which said aromatic liquid compound is contacted with a zeolitic adsorbent material

Methodology Applied
Scientific EffectZeolite: Zeolite

Data Source

PatentUS20230173454A1Purification of aromatic liquids
Publication Date: 2023.06.08 EASTMAN CHEMICAL HTF GMBH
  • US20230173454A1 patent drawing
  • US20230173454A1 patent drawing

AI summary

The present invention concerns a process for purifying an aromatic liquid compound, said process comprising at least a step in which said aromatic liquid compound is contacted with a zeolitic adsorbent material.The present invention also concerns the use of a zeolitic adsorbent material for purifying an aromatic liquid compound.