Amine-Impregnated Zeolite Bitumen Composites for Durable Adhesion

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Amine-based liquid antistripping agents used in asphalt lose efficacy over time, particularly at high temperatures, leading to reduced adhesion between bitumen and aggregates, thus affecting the durability of asphalt.

Innovation Solution

Amine-impregnated zeolites are used as solid antistripping agents, where amine molecules are gradually released from the zeolite pores into the bitumen matrix, enhancing durability by maintaining their effectiveness over a longer period.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If amine-based liquid antistripping agents are used in asphalt, then adhesion between bitumen and aggregates is improved, but the agents lose efficacy over time at high temperatures

Engineering Contradiction:
Improveadhesion between bitumen and aggregatesVSAvoiddurability of antistripping agent
Core Design Contradiction:
ReliabilityVSDuration of action of stationary object

Solution Approach 1:

The patent uses zeolite, a porous material, as a carrier to load amine molecules into its pore structure. This allows the amine to be stored within the zeolite framework and gradually released over time, preventing rapid degradation while maintaining adhesion performance. The porous structure provides both storage capacity and controlled release mechanism.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent creates a composite material combining zeolite (inorganic porous framework) with amine molecules (organic antistripping agent). This composite structure leverages the thermal stability and structural integrity of zeolite while incorporating the adhesion-enhancing properties of amine, resulting in a material that maintains efficacy at high temperatures over extended periods.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If amine molecules are gradually released from zeolite pores into bitumen, then durability is enhanced over time, but the complexity of the antistripping agent increases

Engineering Contradiction:
Improvedurability of antistripping agentVSAvoidstructure of antistripping agent
Core Design Contradiction:
Duration of action of stationary objectVSDevice complexity

Solution Approach 1:

The zeolite-amine composite is designed to automatically release amine molecules in response to environmental conditions (temperature, moisture) without requiring external control mechanisms. The porous structure inherently provides the release pathway, and the amine gradually diffuses out when conditions favor release, creating a self-regulating system that extends durability without adding operational complexity.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The amine-impregnated zeolites provide increased durability to asphalt by ensuring consistent antistripping performance despite exposure to high temperatures and moisture, reducing moisture-induced damage at the bitumen-aggregate interface.

Implementation Method 1

the amine molecules loaded into the zeolite's pores can be gradually released into the matrix of bitumen

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12565573B2Bitumen composites with impregnated zeolites
Publication Date: 2026.03.03 THE ARIZONA BOARD OF REGENTS ON BEHALF OF THE UNIV OF ARIZONA
  • US12565573B2 patent drawing
  • US12565573B2 patent drawing
  • US12565573B2 patent drawing

AI summary

A bitumen composite includes an amine-impregnated zeolite and bitumen. Forming the bitumen composite includes combining bitumen and an amine-impregnated zeolite to yield a mixture, heating the mixture to yield the bitumen composite.