Zeolite Adsorption for CO2 Gas Insulation Stability

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The use of CO2 as an insulation gas in gas insulation apparatuses leads to reduced insulation and arc-extinguishing performance due to dissociation, resulting in a gradual decrease in CO2 levels and an increase in CO levels, which requires frequent maintenance and gas replenishment, unlike SF6, which has superior recombination properties.

Innovation Solution

Incorporating zeolite into the gas insulation apparatus to adsorb CO2 molecules before use and trap CO molecules generated by dissociation, maintaining the gas filling pressure and preventing a decrease in insulation and arc-extinguishing performance, while also adsorbing HF molecules to prevent further reactions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If CO2 gas is used as the insulation gas, then the global warming effect is reduced compared to SF6 gas, but the insulation performance and arc-extinguishing performance deteriorate due to dissociation and lack of recombination

Engineering Contradiction:
Improveglobal warming effectVSAvoidinsulation performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

Zeolite is introduced as an intermediary substance that mediates between the dissociation process and the insulation gas. The zeolite captures reactive species (oxygen ions, CO molecules) generated during dissociation, preventing them from degrading the insulation performance while allowing CO2 to maintain its environmental advantages.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The harmful cracked gases (CO, oxygen ions) are extracted from the insulation gas system by the zeolite material. This removal process prevents the accumulation of substances that would otherwise degrade the insulation and arc-extinguishing performance over time.

Inventive Principle:
Principle #2Taking out (Extraction)

2Object-affected harmful factors

If CO2 gas is used as the insulation gas, then the environmental impact is reduced, but the arc-extinguishing performance decreases due to generation of cracked gas without recombination

Engineering Contradiction:
Improveenvironmental impactVSAvoidarc-extinguishing performance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

Zeolite acts as a mediator that intercepts the dissociation products (CO molecules and oxygen ions) before they can accumulate and compromise arc-extinguishing performance. This allows CO2 to be used as the insulation gas while maintaining reliable arc extinction capability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The dissociation of CO2, which initially appears harmful due to performance degradation, is converted into a beneficial process. The zeolite captures the dissociation products, and the remaining CO2 maintains its excellent dielectric strength and arc quenching properties, while the captured cracked gases are removed from the system.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Stability of the object's composition

If CO2 gas is used as the insulation gas, then the recombination rate after dissociation is lower than SF6, but this leads to gradual reduction of CO2 amount and increase in CO amount

Engineering Contradiction:
Improvechemical stabilityVSAvoidCO2 amount
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The zeolite material extracts CO molecules and oxygen ions from the insulation gas system. This continuous extraction prevents the gradual accumulation of CO and loss of CO2 that would otherwise occur due to the low recombination rate, thereby maintaining the original gas composition and quantity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system discards the harmful cracked gases (CO) through zeolite absorption while recovering and maintaining the beneficial CO2 insulation gas. This selective removal process preserves the CO2 quantity and prevents composition degradation over time.

Inventive Principle:
Principle #34Discarding and recovering

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The zeolite effectively suppresses the deterioration of insulation and arc-extinguishing performance by maintaining CO2 levels and adsorbing CO and HF gases, thereby extending the operational life of the gas insulation apparatus and reducing global warming impact compared to SF6.

Implementation Method 1

Incorporating zeolite into the gas insulation apparatus to adsorb CO2 molecules before use

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

trap CO molecules generated by dissociation

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

adsorbing HF molecules to prevent further reactions

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentEP2445068B1Gas insulation apparatus
Publication Date: 2017.02.08 KK TOSHIBA
  • EP2445068B1 patent drawing
  • EP2445068B1 patent drawing
  • EP2445068B1 patent drawing

AI summary

A gas insulation apparatus(e.g., a gas circuit breaker) includes a high-voltage unit, a zeolite(20) and an insulation gas in a closed vessel(10). The insulation gas is CO2 gas or a gas including CO2 gas as the main component. The zeolite (20) is contained in a zeolite case(21) and is placed under an insulation gas atmosphere. CO2 is adsorbed on the zeolite (20) before use of the gas insulation apparatus.