Copper Ion-Exchanged Zeolite Gas Adsorption Device

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Solution Overview

Problem

Existing gas adsorption devices for sealed containers and thermal insulators face issues with gas-adsorptive substance consumption due to air exposure, low nitrogen adsorption capacity, and increased manufacturing complexity, particularly with moisture adsorption leading to reduced adsorption efficiency and durability.

Innovation Solution

A gas adsorption device utilizing copper ion-exchanged ZSM-5 type zeolite, combined with a primary material of lower gas barrier property, is used to suppress air exposure and enhance gas adsorption capacity, maintaining high vacuum and purity within sealed containers and thermal insulators.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If gas-adsorptive substance is exposed to air before application, then the substance can be handled easily, but the gas-adsorptive substance is consumed by adsorbing air components and moisture

Engineering Contradiction:
Improvehandling easeVSAvoidgas-adsorptive substance consumption
Core Design Contradiction:
Ease of operationVSLoss of substance

Solution Approach 1:

A protective coating layer is applied to the gas-adsorptive substance (copper ion-exchanged ZSM-5 zeolite) to act as an intermediary barrier. This coating prevents direct contact between the zeolite and air/moisture during handling and storage, while still allowing the zeolite to perform its gas adsorption function when needed. The coating serves as a mediator that protects the active substance without completely isolating it from its intended environment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The protective coating is applied in advance (before the zeolite is put to use) to prevent the harmful action of air and moisture on the gas-adsorptive substance. This preliminary protective measure ensures that the zeolite does not consume its adsorption capacity during storage or handling, maintaining its effectiveness for the intended application.

Inventive Principle:
Principle #9Preliminary anti-action

2Loss of substance

If barrier containers are used to prevent air exposure, then gas adsorption material consumption is reduced, but manufacturing complexity increases

Engineering Contradiction:
Improvegas adsorption material consumptionVSAvoidcontainer structure complexity
Core Design Contradiction:
Loss of substanceVSDevice complexity

Solution Approach 1:

Instead of using complex rigid barrier containers, the invention employs a thin film protective coating applied directly to the gas-adsorptive substance. This flexible film approach provides effective barrier protection against air and moisture while being simpler to apply and integrate than rigid container structures. The thin film coating reduces manufacturing complexity compared to designing and assembling separate barrier containers.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces gas adsorption material consumption, achieves high vacuum and purity states, and extends the thermal insulation performance over time by selectively adsorbing air components and moisture, thereby improving the durability and efficiency of gas adsorption within sealed environments.

Implementation Method 1

a gas adsorption device which includes at least copper ion-exchanged ZSM-5 type zeolite and a primary material

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

primary material having a lower gas barrier property than the outer container does

Methodology Applied
Scientific EffectGas barrier property: Diffusion Barrier

Data Source

PatentUS10247350B2Sealed container, thermal insulator, and gas adsorption device
Publication Date: 2019.04.02 PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO LTD
  • US10247350B2 patent drawing
  • US10247350B2 patent drawing
  • US10247350B2 patent drawing

AI summary

A sealed container (1) includes at least an outer container (2) and a gas adsorption device (4) being provided in a sealed space (3) within the outer container (2) and being capable of adsorbing a gas. The gas adsorption device (4) includes at least a copper ion-exchanged ZSM-5 type zeolite and a primary material having a lower gas barrier property than the outer container (2) does.