Zeolite-Polyolefin Compatibilizer for Polymer Matrix Integration

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Solution Overview

Problem

The incorporation of zeolites into polymer matrices is hindered by poor compatibility, leading to low zeolite content and energy-intensive mixing processes, making it difficult to achieve high proportions of zeolites in industrial applications.

Innovation Solution

Modified zeolite crystals are developed by incorporating a polymeric compatibilizer, specifically a functional polyolefin, which improves compatibility with organic polymers, allowing for higher zeolite incorporation and reduced energy consumption during mixing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If zeolites are incorporated into polymer matrices using conventional mixing techniques, then zeolite adsorption function is achieved, but poor compatibility leads to low zeolite content and high energy consumption

Engineering Contradiction:
Improvezeolite contentVSAvoidmixing energy consumption
Core Design Contradiction:
Quantity of substanceVSUse of energy by moving object

Solution Approach 1:

A compatibilizer is introduced as an intermediary substance between the inorganic zeolite and the organic polymer matrix. The compatibilizer has affinity for both materials, reducing interfacial tension and improving dispersion. This mediator enables higher zeolite loading (up to 80-90 wt%) while significantly reducing mixing energy requirements and avoiding agglomeration.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Quantity of substance

If high proportion of zeolite is incorporated into polymer matrix, then adsorption capacity is improved, but compatibility issues cause processing difficulties and increased viscosity

Engineering Contradiction:
Improvezeolite proportionVSAvoidmixing ease
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The compatibilizer acts as a lubricating intermediary that facilitates the mixing process. By reducing interfacial adhesion between zeolite particles and polymer matrix, the compatibilizer prevents excessive viscosity build-up and makes high-proportion mixing (80-90% zeolite) as easy to process as conventional low-proportion formulations.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If conventional mixing techniques are used for zeolite incorporation, then processing is straightforward, but the process is time-consuming and energy-intensive

Engineering Contradiction:
Improveprocessing simplicityVSAvoidmixing time
Core Design Contradiction:
Ease of manufactureVSLoss of time

Solution Approach 1:

The compatibilizer enables rapid mixing by reducing interfacial friction and improving flow characteristics. Formulations with 80-90% zeolite content can be processed in the same or shorter timeframes as conventional formulations, eliminating the time penalty typically associated with high-filler loading while maintaining manufacturing simplicity.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The modified zeolite crystals exhibit enhanced compatibility and mechanical properties, enabling easier incorporation into polymer matrices with reduced energy consumption and increased zeolite content, resulting in improved adsorption and mechanical properties of the composite materials.

Implementation Method 1

modified zeolite crystals comprising zeolite crystals and a polymeric compatibilizer

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

when the zeolite is used as an active ingredient for adsorption purposes such as water adsorption or the adsorption of volatile organic compounds

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20230211314A1Zeolites with improved compatibility
Publication Date: 2023.07.06 ARKEMA FRANCE SA
  • US20230211314A1 patent drawing

AI summary

The invention relates to modified zeolite crystals comprising zeolite crystals and from 0.5% to 20%, by weight, endpoints included, relative to the total weight of modified zeolite crystals, of at least one polymeric compatibilizer, more particularly a functional polyolefin.The invention also relates to the use of the modified zeolite crystals according to the invention as a filler in a polymer matrix, for example for the preparation of composite materials.