Zinc-Amino Acid Complexes for Oral Bacterial Aggregation

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Solution Overview

Problem

Current oral care compositions using zinc salts often suffer from poor taste, mouthfeel, fluoride delivery, foaming, and cleaning efficacy, and lack selective bacterial aggregation, which are essential for effective oral hygiene and health.

Innovation Solution

The development of oral care compositions containing zinc(II)-amino acid complexes, such as zinc-lysine or zinc-arginine complexes, which form soluble cationic moieties that promote selective bacterial aggregation and immune clearance, thereby enhancing oral hygiene and health without the drawbacks of traditional zinc-based products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If traditional zinc salts are used in oral care compositions, then antibacterial activity is achieved, but taste and mouthfeel deteriorate

Engineering Contradiction:
Improveantibacterial activityVSAvoidtaste and mouthfeel
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

Amino acids serve as intermediary ligands that complex with zinc ions, creating a bridging structure that maintains zinc's antibacterial properties while masking its harsh taste and improving mouthfeel. The amino acid ligand acts as a mediator between the zinc ion and the oral environment.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The chemical form of zinc is changed from simple salts to coordinated complexes with amino acids. This parameter change in molecular structure fundamentally alters the sensory properties while preserving the biological activity of zinc against oral bacteria.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional zinc salts are used, then antibacterial effects are achieved, but fluoride delivery and foaming performance worsen

Engineering Contradiction:
Improveantibacterial effectsVSAvoidfluoride delivery and foaming performance
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The zinc-amino acid complex formulation is designed to perform multiple functions simultaneously: antibacterial activity, fluoride delivery, and foaming performance. The complex structure allows zinc to maintain its antimicrobial properties while the formulation accommodates fluoride compounds and surfactants for enhanced multi-functionality.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Reliability

If free metal ions are used for bacterial aggregation, then aggregation effect is achieved, but selectivity deteriorates

Engineering Contradiction:
Improvebacterial aggregation effectVSAvoidselectivity
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The zinc-amino acid complex exhibits localized properties at the bacterial surface through specific interactions. The complex targets bacterial cells with selective affinity, creating a localized aggregation effect at the bacterial interface while maintaining selectivity against specific oral bacteria species.

Inventive Principle:
Principle #3Local quality

4Reliability

If soluble zinc salts are used, then bioavailability is improved, but astringency and cosmetic appearance worsen

Engineering Contradiction:
ImprovebioavailabilityVSAvoidastringency and cosmetic appearance
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The invention creates a composite material system where zinc ions are coordinated with amino acid ligands. This composite structure combines the bioavailability benefits of soluble zinc with the improved sensory and cosmetic properties of the amino acid component, resulting in a material that exhibits properties superior to either component alone.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compositions effectively reduce bacterial biofilm, plaque, gingivitis, and acid erosion, inhibit tooth decay, and improve oral health by aggregating and clearing oral bacteria, while maintaining a favorable taste and mouthfeel.

Implementation Method 1

these complexes can effectively and selectively promote the aggregation of bacteria

Methodology Applied
Scientific EffectBacterial aggregation: Coagulation

Data Source

PatentEP3386466B1Metal amino acid complexes for bacterial aggregation
Publication Date: 2022.05.11 COLGATE PALMOLIVE CO

AI summary

Disclosed herein are methods of promoting the aggregation and/or immune clearance of oral bacteria using oral care compositions comprising metal-amino acid complexes.