Zinc Oxide Composite Particles with Polysilsesquioxane Coating

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Solution Overview

Problem

Current zinc oxide-containing composite particles lack sufficient acid resistance, which affects their performance in cosmetic and ultraviolet-shielding applications.

Innovation Solution

A zinc oxide-containing composite particle is developed, comprising a porous silica particle with zinc oxide particles enclosed within and a polysilsesquioxane coating layer, which enhances acid resistance and prevents zinc ion dissolution.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If zinc oxide is incorporated in cosmetics for UV-A shielding, then UV-A shielding property is improved, but zinc ion dissolution occurs which impairs product properties

Engineering Contradiction:
ImproveUV-A shielding propertyVSAvoidzinc ion dissolution
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent introduces an intermediary substance (coating material such as silica, alumina, or polymer coatings) that mediates between zinc oxide and the cosmetic environment. This coating layer acts as a barrier that prevents direct contact between zinc ions and the cosmetic formulation, thereby eliminating the harmful dissolution effect while preserving the UV-A shielding function of zinc oxide.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent employs composite material structures where zinc oxide is combined with coating materials to form a core-shell or composite particle system. The composite structure integrates the UV-blocking capability of zinc oxide with the protective and stabilizing properties of the coating material, achieving both function preservation and harm elimination.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If conventional coating methods are used on zinc oxide particles, then zinc ion dissolution is inhibited, but acid resistance remains insufficient

Engineering Contradiction:
Improvezinc ion dissolutionVSAvoidacid resistance
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition and structural properties of the coating layer. Specifically, the coating materials are selected and formulated to have high acid resistance parameters, and the coating thickness and cross-linking density are optimized to enhance protective performance in acidic cosmetic environments while maintaining inhibition of zinc ion dissolution.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite particle exhibits high acid resistance, allowing for uniform dispersion in acidic solutions and maintaining UV-A shielding properties over time, even in aqueous cosmetics.

Implementation Method 1

a coating layer covering the porous silica particle, the coating layer containing a polysilsesquioxane

Methodology Applied
Scientific EffectCoating: Coatings

Implementation Method 2

zinc oxide particles enclosed within the porous silica particle

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Data Source

PatentEP3305728B1Zinc oxide-containing composite particles, composition for blocking UV rays, and cosmetic material
Publication Date: 2019.09.18 NIPPON SHEET GLASS CO LTD
  • EP3305728B1 patent drawingFigure 1

AI summary

A zinc oxide-containing composite particle (1) according to the present invention includes a porous silica particle (10), zinc oxide particles (20), and a coating layer (30). The zinc oxide particles (20) are enclosed within the porous silica particle (10). The coating layer (30) covers the porous silica particle (10) and contains a polysilsesquioxane. The zinc oxide-containing composite particle (1) can thus be provided as a particle having high acid resistance.