Zinc-Based Sealing for Dyed Anodized Layers

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional anodized layers in consumer portable electronic devices are insufficient in protecting dyed enclosures from premature color loss due to ultraviolet light exposure, as existing nickel-based seals are toxic and fail to adequately attenuate UV light, leading to color degradation.

Innovation Solution

Incorporating zinc into the anodized layers through a zinc-based sealing process, dyeing process, or buffer solution, resulting in a zinc concentration of 3 wt % to 6 wt % at the external surface, which strongly attenuates UV light and stabilizes colorants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional nickel-based seals are used to seal the anodized layer, then the dye color is retained within the pores, but the sealant is toxic and fails to adequately attenuate UV light, leading to color degradation

Engineering Contradiction:
Improvedye color retentionVSAvoidUV light exposure and toxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameter of the sealant from nickel-based to zinc-based, achieving both non-toxicity and superior UV attenuation. The zinc concentration is optimized to 3-6 wt% at the external surface, which provides sufficient UV protection while maintaining non-toxic properties. This parameter change resolves the contradiction by finding a material composition that simultaneously achieves toxicity reduction and UV protection enhancement.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite sealing structure where zinc is incorporated into the anodized layer matrix, forming a composite material with enhanced UV attenuation properties. The zinc-containing sealant combines the sealing function with the UV protection function, creating a multi-functional composite that addresses both the toxicity issue and the UV protection insufficiency of conventional nickel-based seals.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If the anodized layer is dyed with desirable colors, then cosmetic appeal is improved, but the dye colors are susceptible to degradation from UV light exposure

Engineering Contradiction:
Improvecolor vibrancy and cosmetic appealVSAvoidcolor stability under light exposure
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent applies zinc-based sealant to the anodized layer before UV exposure occurs, creating a protective barrier that cushions the dye colors from UV damage. The zinc concentration of 3-6 wt% at the external surface provides preemptive UV attenuation, preventing color degradation before it can occur. This prior cushioning approach allows the use of vibrant dyes while protecting them from future UV exposure.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Solution Approach 2:

The zinc-based sealant acts as an intermediary layer between the UV light and the dye-containing anodized layer. This intermediary substance absorbs and attenuates UV radiation, preventing direct interaction between UV photons and the dye molecules. The zinc sealant thus mediates the interaction, allowing color vibrancy to be maintained while protecting against UV-induced degradation.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If zinc concentration is increased to improve UV attenuation, then lightfastness is improved, but manufacturing complexity and cost may increase

Engineering Contradiction:
Improvelightfastness and UV protectionVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent merges the sealing function and the UV protection function into a single zinc-based sealing process. By using zinc compounds that serve both as sealants and UV attenuators, the manufacturing process does not require separate steps for sealing and UV protection. The zinc concentration of 3-6 wt% is achieved through standard sealing procedures, avoiding additional manufacturing complexity while providing both sealing and UV protection benefits.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent employs zinc-based sealants that are cost-effective and can be applied through conventional sealing processes. Zinc compounds are generally more affordable than many specialized UV protection coatings, and the sealing process itself is a established, low-cost industrial process. This approach provides superior UV protection without significantly increasing manufacturing cost or complexity.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The zinc-based solution effectively retains dye colors, providing improved lightfastness and corrosion resistance, with minimal color shift and equivalent performance to nickel-based seals, while being non-toxic and cost-effective.

Implementation Method 1

dyeing the anodized layer by exposing pores of the anodized layer to a dye

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

sealing the dye within the pores by exposing the anodized layer to a zinc-based sealing solution

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

an external surface of the anodized layer having the pores that are sealed includes an amount of zinc between about 3 wt % to about 6 wt %

Methodology Applied
Scientific EffectUV light attenuation: Absorption (EM radiation)

Data Source

PatentUS11371157B2Process for incorporating zinc into a dyed anodized layer for protecting dye colorants from light exposure
Publication Date: 2022.06.28 APPLE INC
  • US11371157B2 patent drawing
  • US11371157B2 patent drawing
  • US11371157B2 patent drawing

AI summary

This application relates to a method for forming an enclosure for a portable electronic device, the enclosure including a metal substrate that is overlaid by an anodized layer. The method includes dyeing the anodized layer by exposing pores of the anodized layer to a dye. The method further includes sealing the dye within the pores by exposing the anodized layer to a zinc-based sealing solution, where an external surface of the anodized layer having the pores that are sealed includes an amount of zinc between about 3 wt % to about 6 wt %.