Zinc-Coated Steel Sheet Surface Conditioning for Better Phosphatability

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Solution Overview

Problem

Existing surface-treated sheet steels with zinc-based coatings face challenges in achieving improved phosphatability, formability, and paint finish due to the limitations of existing skin-pass rolling processes.

Innovation Solution

Perform skin-pass rolling with a degree of skin-pass greater than 1%, specifically greater than 1.2% or 1.4%, to alter the dimensions of zinc grains in embossed regions, causing microfractures and enhancing the surface area, thereby improving phosphatability, formability, and paint finish.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If skin-pass rolling is performed with conventional degree of skin-pass (≤1%), then the surface structure is formed, but the zinc grains are not sufficiently altered and microfractures are not generated

Engineering Contradiction:
Improvesurface structure formationVSAvoidphosphatability
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by increasing the degree of skin-pass from conventional values (≤1%) to greater than 1% (specifically 1.2-2.0%). This parameter change causes the zinc grains in the embossed regions to be altered in dimension and generates microfractures, thereby improving phosphatability while maintaining surface structure formation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The skin-pass rolling process is performed as a preliminary action before phosphating to pre-alter the zinc grain structure and create microfractures in the embossed regions. This preliminary modification of the surface structure enhances subsequent phosphating performance by providing increased surface area and improved chemical reactivity

Inventive Principle:
Principle #10Preliminary action

2Reliability

If skin-pass rolling is performed with high degree of skin-pass (>1.4%), then microfractures and surface area increase are achieved, but the forming process requires higher mechanical force

Engineering Contradiction:
ImprovephosphatabilityVSAvoidmechanical force
Core Design Contradiction:
ReliabilityVSForce

Solution Approach 1:

The patent applies local quality by creating microfractures and altering zinc grains specifically in the embossed regions while leaving the unembossed regions relatively unchanged. This localized modification concentrates the surface area increase and chemical reactivity enhancement where needed, without requiring uniform high force across the entire sheet during forming

Inventive Principle:
Principle #3Local quality

3Ease of manufacture

If conventional skin-pass rolling is used, then the process is simple, but the chemical reactivity and surface area are insufficient for improved phosphatability

Engineering Contradiction:
Improveprocess simplicityVSAvoidchemical reactivity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent modifies the conventional skin-pass rolling process by changing the degree of skin-pass parameter to greater than 1%. This simple parameter adjustment transforms the process outcome to generate microfractures and increase surface area, thereby enhancing chemical reactivity for improved phosphatability while maintaining process simplicity

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process results in better phosphatability, formability, and paint finish by generating targeted microfractures in the zinc grains, increasing surface area and chemical reactivity, and ensuring homogeneous phosphate layer formation.

Implementation Method 1

due to the force exerted by the skin-pass rolling the zinc grains in the embossed region are altered in dimension relative to the zinc grains in the unembossed region

Methodology Applied
Scientific EffectMechanical force: Mechanical Force

Implementation Method 2

The resulting 'microfractures' in the intermetallic phase can ensure lower coefficients of friction and thus lower-wear forming

Methodology Applied
Scientific EffectMicrofractures: Fracture Mechanics

Implementation Method 3

making it possible to alter the zinc grains in the embossed region, wherein the especially 'targeted' effect, for example destroying or damaging the zinc grains in the embossed region, makes it possible to generate advantageous further 'microfractures' on the surface of the coating additional to those already formed in the intermetallic phase which can preferably enhance chemical reactivity by increasing the surface area within the embossed regions

Methodology Applied
Scientific EffectSurface area increase:

Implementation Method 4

The eutectic mixture or the intermetallic phase present in the eutectic mixture formed in the zinc-based coating comprising Mg in the hot-dip coating process is (markedly) harder than the surrounding matrix (coating) and fractures under the mechanical force exerted in the context of the skin-pass rolling and/or forming process

Methodology Applied
Scientific EffectEutectic mixture:

Implementation Method 5

The resulting 'microfractures' in the intermetallic phase can ensure lower coefficients of friction and thus lower-wear forming

Methodology Applied
Scientific EffectFriction reduction: Friction

Data Source

PatentUS12472544B2Method for producing a surface-treated and surface-conditioned steel sheet
Publication Date: 2025.11.18 THYSSENKRUPP STEEL EUROPE AG PATENTE PATENT DEPARTMENT
  • US12472544B2 patent drawing
  • US12472544B2 patent drawing

AI summary

The present disclosure relates to a process for producing a surface-treated and surface-finished sheet steel. A sheet steel having a zinc-based coating is provided, wherein zinc grains are distributed within the coating. The surface-treated sheet steel are skin-pass rolled to form embossed regions and unembossed regions on the surface of the sheet steel provided with a zinc-based coating. Skin-pass rolling is performed with a degree of skin-pass greater than 1% in such a way that due to the force exerted by the skin-pass rolling the zinc grains in the embossed region are altered in dimension relative to the zinc grains in the unembossed region.