Zirconia Block Color Gradient via Layered Powder Mixing

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Solution Overview

Problem

Current methods for manufacturing zirconia blocks for artificial teeth require complex processes like pigment treatment and surface treatment to achieve color gradients similar to natural teeth, often using porcelain powder or liquid color sets, which are time-consuming and prone to color changes.

Innovation Solution

A method involving the preparation of colored and white zirconia-based powders mixed in varying ratios, sequentially injected into a mold with pressure application and calcination, allowing for a color gradient within the zirconia block without external colorants, utilizing organic binders and a de-binding process to achieve a uniform density and desired color gradient.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If several complex processes such as pigment treatment and surface treatment are used after zirconia block processing to express natural tooth colors, then the aesthetic function is improved, but the manufacturing time increases and productivity decreases

Engineering Contradiction:
Improvecolor gradientVSAvoidmanufacturing time
Core Design Contradiction:
ShapeVSProductivity

Solution Approach 1:

The color gradient is incorporated into the zirconia block during the initial mixing and molding stages, before the actual tooth fabrication process. By preparing multiple raw materials with different colored zirconia powder concentrations in advance and stacking them sequentially, the patent eliminates the need for subsequent pigment treatment and surface treatment processes, thereby reducing manufacturing time while achieving natural tooth aesthetics

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent combines the coloration process with the zirconia block formation process itself. Instead of treating color application as a separate subsequent step, the colored and white zirconia powders are mixed in varying ratios and molded together to form a single integrated block with inherent color gradient, merging two previously separate operations into one

Inventive Principle:
Principle #5Merging (Combining)

2Shape

If several complex processes such as pigment treatment and surface treatment are used after zirconia block processing to express natural tooth colors, then the aesthetic function is improved, but the process complexity increases

Engineering Contradiction:
Improvecolor gradientVSAvoidprocess complexity
Core Design Contradiction:
ShapeVSDevice complexity

Solution Approach 1:

The color gradient structure is established in advance during raw material preparation by mixing colored and white zirconia powders in different ratios. This preliminary configuration of color layers within the raw materials eliminates the need for complex subsequent pigment application and surface treatment processes, simplifying the overall manufacturing workflow

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The zirconia block is divided into multiple raw materials with different color concentrations (colored zirconia-based powder mixed with white zirconia-based powder in varying ratios). These segmented raw materials are then stacked in a specific sequence during molding to create the final color gradient, breaking down the complex coloration task into manageable discrete components

Inventive Principle:
Principle #1Segmentation

3Shape

If porcelain powder or liquid color set is used to express natural tooth colors, then the aesthetic function is improved, but the reliability decreases due to color changes

Engineering Contradiction:
Improvecolor gradientVSAvoidcolor consistency
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent changes the fundamental parameter of color application from external coating (porcelain powder or liquid color set) to internal composition (colored zirconia powder mixed with white zirconia powder). By varying the concentration ratio of colored to white powder within the zirconia matrix itself, the color gradient is inherently built into the material structure, ensuring color consistency without the reliability issues of external colorants

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite zirconia material system combining colored zirconia-based powder and white zirconia-based powder in different ratios. This composite approach allows the color gradient to be an intrinsic property of the material composition rather than a surface treatment, improving color stability and eliminating the need for separate porcelain or liquid color applications

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the creation of zirconia blocks with a natural tooth color gradient, reducing manufacturing time by 30% and ensuring consistent color, enhancing patient satisfaction by eliminating the need for additional treatments and minimizing color change concerns.

Implementation Method 1

applying a pressure to the compression mold into which the plurality of raw materials are injected to mold

Methodology Applied
Scientific EffectCompression: Compression

Implementation Method 2

performing a cold isostatic pressing (CIP) process in order to maintain a uniform internal density distribution of the molding result before the calcining

Methodology Applied
Scientific EffectCold isostatic pressing: Compression

Implementation Method 3

calcining a molding result

Methodology Applied
Scientific EffectCalcining: Heating

Data Source

PatentUS9687325B2Method of manufacturing zirconia block for artificial tooth having color gradient
Publication Date: 2017.06.27 DMAX CO LTD
  • US9687325B2 patent drawing
  • US9687325B2 patent drawing
  • US9687325B2 patent drawing

AI summary

There is provided a method of manufacturing a zirconia block for an artificial tooth having a color gradient. The method includes: preparing colored zirconia-based powder and white zirconia-based powder; preparing a plurality of raw materials in which the colored zirconia-based powder and the white zirconia-based powder are mixed in different weight ratios by mixing the colored zirconia-based powder and the white zirconia-based powder while changing a mixing ratio in order to express a desired color gradient; sequentially injecting the plurality of raw materials into a compression mold or a mold frame to mold in increasing or decreasing order of content of the colored zirconia-based powder of the raw material; and calcining a molding result. According to the present invention, it is possible to express aesthetics of a natural tooth by implementing a color gradient of the natural tooth in the zirconia block itself without using porcelain powder or a liquid color set.