Activated Carbon Filter with Zirconium for Nitrate Adsorption

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Solution Overview

Problem

Existing activated carbon filters struggle to effectively filter nitrates, leading to insufficient adsorption efficiency.

Innovation Solution

A filter unit comprising activated carbon granules coated with a thermoplastic binder and a zirconium compound, where the zirconium compound is bound to the binder during heating, creating a shaped adsorption body with enhanced micropores for improved adsorption efficiency, particularly in filtering nitrates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional activated carbon is used in filter units, then the filter structure is simple and easy to manufacture, but the adsorption efficiency for nitrates is insufficient

Engineering Contradiction:
Improveadsorption efficiencyVSAvoidfilter composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by combining activated carbon granules with a thermoplastic binder and a zirconium compound to create an adsorption body that achieves superior nitrate adsorption performance. The composite structure allows the zirconium compound to enhance the adsorption capacity while the thermoplastic binder provides structural integrity, resolving the contradiction between simple composition and high adsorption efficiency.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by heating the mixture of activated carbon, thermoplastic binder, and zirconium compound to a temperature above the plastic range of the binder. This thermal treatment activates the binder to function as an adsorbent and binds the zirconium compound to the activated carbon, transforming the material properties to achieve enhanced nitrate removal performance.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If activated carbon granules are coated with thermoplastic binder and heated beyond plastic range, then the adsorption efficiency improves, but the manufacturing process becomes more complex

Engineering Contradiction:
Improveadsorption efficiencyVSAvoidproduction process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-coating the activated carbon granules with the thermoplastic binder before adding the zirconium compound and forming the shaped body. This preliminary coating ensures uniform distribution and proper adhesion, simplifying the subsequent heating process and ensuring consistent adsorption performance without requiring complex multi-step manufacturing procedures.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If the zirconium compound is added to the activated carbon and binder mixture, then nitrate reduction increases by more than 3%, but the material composition becomes more complex

Engineering Contradiction:
Improvenitrate reduction efficiencyVSAvoidadsorption body composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent uses the thermoplastic binder as an intermediary substance that facilitates the integration of the zirconium compound with the activated carbon. The binder acts as a carrier and binding agent, allowing the zirconium compound to be uniformly distributed and bound to the activated carbon granules, thereby achieving enhanced nitrate adsorption without creating an overly complex direct combination of all three materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The addition of a zirconium compound to the activated carbon and binder significantly enhances the filter's adsorption efficiency, resulting in a nitrate reduction of more than 3% compared to conventional filters.

Implementation Method 1

Adsorbents are preferably water-insoluble porous materials that, due to their large surface area, bind water or other molecules to themselves through physical forces

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

The activated carbon granules are coated with the thermoplastic binder under the influence of heat. The zirconium compound is added to the binder-coated activated carbon granules. The resulting mixture is compressed and then heated beyond the plastic range of the binder

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 3

These materials are used for adsorption. Preferred adsorbents are bentonite, aluminum oxide, silica gel, zeolites, and especially preferably activated carbon

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 4

Activated carbon is an open-pored, fine-grained coal with a large internal surface area. The pores are interconnected (open-pored). The internal surface area is preferably between 300 and 2000 m2/g of coal

Methodology Applied
Scientific EffectPorosity: Porosity

Data Source

PatentEP4574238A1Filter assembly
Publication Date: 2025.06.25 WESTA HOLDING GMBH & CO KG
  • EP4574238A1 patent drawingFigure 1~2
  • EP4574238A1 patent drawingFigure 3
  • EP4574238A1 patent drawing

AI summary

Filter unit (1, 1'), in particular for the fine filtration of fluids and gases, comprising at least one inlet side (2), at least one outlet side (5) and an adsorption body (4) in the form of a shaped body which consists of an adsorption agent (4.1), in particular of grains of activated carbon, a binder (4.2) and a zirconium compound (4.3), wherein the adsorption agent (4.1) is coated with the binder (4.2) and further binds the zirconium compound (4.3) in the shaped body.