ZnO Piezoelectric Layer Doping for Higher Coupling Efficiency

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Solution Overview

Problem

Existing piezoelectric devices face challenges in achieving high mechanical-to-electrical and electrical-to-mechanical energy conversion efficiency, particularly in applications requiring high sensitivity and responsiveness to pressure.

Innovation Solution

A piezoelectric device with a ZnO-based piezoelectric layer having a wurtzite crystal structure doped with specific amounts of metals like Mg or Ca to enhance the electromechanical coupling coefficient, specifically targeting a squared value of 6.5% or more in the thickness vibration mode.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional piezoelectric layer is used, then the device structure is simple, but the electromechanical coupling coefficient is insufficient for high sensitivity applications

Engineering Contradiction:
Improveelectromechanical coupling coefficientVSAvoidpiezoelectric layer composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the concentration of metal atoms (Mg, Ca, Sr, Ba) doped into the ZnO piezoelectric layer. By optimizing the doping concentration within specific ranges, the electromechanical coupling coefficient is enhanced to achieve high sensitivity in thickness vibration mode, resolving the contradiction between maintaining simple structure and improving performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite materials by doping metal atoms into the ZnO piezoelectric layer to form a composite structure. This composite approach combines the advantages of ZnO (wurtzite crystal structure, piezoelectric properties) with the benefits of alkaline earth metal doping, resulting in enhanced electromechanical coupling while maintaining the fundamental simplicity of the device architecture.

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If the piezoelectric layer is optimized for high conversion efficiency, then energy conversion ability improves, but manufacturing precision requirements increase

Engineering Contradiction:
Improvemechanical/electrical conversion efficiencyVSAvoidmetal doping concentration control
Core Design Contradiction:
Use of energy by moving objectVSManufacturing precision

Solution Approach 1:

The patent establishes specific parameter ranges for metal doping concentration (e.g., Mg content, Ca content, Sr content, Ba content) that optimize mechanical/electrical conversion efficiency. By defining these precise parameter ranges, the patent balances the need for high conversion efficiency with achievable manufacturing precision, ensuring that the doping concentration can be controlled within practical limits during fabrication.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The doping of ZnO-based piezoelectric layers with Mg or Ca significantly improves the conversion efficiency between electrical and mechanical energy, enhancing the electromechanical coupling coefficient by up to 25% compared to undoped layers.

Implementation Method 1

The piezoelectric effect is a phenomenon in which microscopic polarization is produced in response to a mechanical stress applied to a substance

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 2

to efficiently convert the applied electrical energy into mechanical deformation

Methodology Applied
Scientific EffectInverse piezoelectric effect: Converse Piezoelectric Effect

Data Source

PatentUS12382836B2Piezoelectric device and method of manufacturing the same
Publication Date: 2025.08.05 NITTO DENKO CORP
  • US12382836B2 patent drawing
  • US12382836B2 patent drawing
  • US12382836B2 patent drawing

AI summary

A piezoelectric device having a high conversion efficiency between electrical energy and mechanical energy is provided. The piezoelectric device has first electrode, a second electrode, and a piezoelectric layer provided between the first electrode and the second electrode, wherein the piezoelectric layer is formed of a ZnO-based material having a wurtzite crystal structure to which a metal that does not cause the piezoelectric layer to exhibit conductivity is added, and wherein a squared value of a electromechanical coupling coefficient in thickness vibration mode is 6.5% or more.