ZnO Electrode Etching Selectivity via Si Mo W Doping

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Solution Overview

Problem

The manufacturing of thin film transistors using IZO as source/drain electrodes faces issues with etching selectivity and process complexity, leading to overhang structures, impurity generation, and increased production costs due to the lack of etching selectivity and reliance on undesirable lift-off processes.

Innovation Solution

The use of zinc oxide electrodes containing Si, Mo, and W allows for selective etching of the channel material and source/drain electrodes through a dry etching process using fluorine gas, simplifying the manufacturing process and ensuring reliability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If IZO is used as source/drain electrodes, then transparency is improved, but etching selectivity deteriorates

Engineering Contradiction:
ImprovetransparencyVSAvoidetching selectivity
Core Design Contradiction:
Illumination intensityVSManufacturing precision

Solution Approach 1:

The patent changes the material composition parameters of the electrode by incorporating Si, Mo, or W into the zinc oxide electrode. This compositional modification alters the etching characteristics while maintaining the transparent properties, thereby resolving the contradiction between transparency and etching selectivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material structure by combining zinc oxide with Si, Mo, or W to create a new electrode material. This composite approach allows the electrode to simultaneously possess the transparency of zinc oxide and the improved etching selectivity provided by the added elements.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If lift-off process is used to manufacture thin film transistor, then source/drain electrodes can be formed, but process complexity increases

Engineering Contradiction:
Improveelectrode formationVSAvoidprocess complexity
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent extracts and eliminates the photoprocess step from the manufacturing sequence by using direct deposition methods with the modified zinc oxide electrode material. This removes the need for photoresist application, patterning, and removal steps that characterize the lift-off process, thereby reducing overall process complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The modified zinc oxide electrode material provides self-service by enabling direct patterning through its improved etching selectivity. The material itself facilitates the formation of precise electrode structures without requiring external photoresist assistance, simplifying the manufacturing process.

Inventive Principle:
Principle #25Self-service

3Reliability

If additional channel protective layer is deposited, then channel protection is improved, but manufacturing cost increases

Engineering Contradiction:
Improvechannel protectionVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The modified zinc oxide electrode material serves multiple functions simultaneously: it provides the conductive electrode function and inherently offers protection to the channel during etching processes. This multi-functionality eliminates the need for separate protective layers, reducing manufacturing cost and process complexity.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent merges the electrode function and channel protection function into a single integrated solution. The modified zinc oxide electrode structure combines both roles, eliminating the need for separate protective layer deposition and reducing overall manufacturing cost.

Inventive Principle:
Principle #5Merging (Combining)

4Productivity

If etching time is controlled without etching selectivity, then source/drain electrodes can be etched, but etching control deteriorates

Engineering Contradiction:
Improveetching speedVSAvoidetching control
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent changes the material composition parameters of the electrode by incorporating Si, Mo, or W into the zinc oxide electrode. This compositional modification alters the etching characteristics while maintaining the transparent properties, thereby resolving the contradiction between transparency and etching selectivity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables selective etching of the semiconductor channel and electrodes, simplifying the manufacturing process and enhancing the reliability of the thin film transistor by utilizing zinc oxide electrodes with Si, Mo, and W, which improves etching control and reduces production costs.

Implementation Method 1

a channel material of a semiconductor layer and the source electrode and the drain electrode can be selectively etched

Methodology Applied
Scientific EffectSelective etching:

Data Source

PatentUS8481362B2Thin film transistor and method for preparing the same
Publication Date: 2013.07.09 LG DISPLAY CO LTD
  • US8481362B2 patent drawing
  • US8481362B2 patent drawing
  • US8481362B2 patent drawing

AI summary

The present invention relates to a thin film transistor and a method of manufacturing the same. More particularly, the present invention relates to a thin film transistor that includes a zinc oxide (ZnO series) electrode having one or more of Si, Mo, and W as a source electrode and a drain electrode, and a method of manufacturing the same.