Zwitterionic Lithium Battery Binder for Adhesion and Low Resistance

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Solution Overview

Problem

Rechargeable lithium batteries face challenges in achieving high adhesive strength of active material layers to current collectors while minimizing electrical resistance, which affects charging speed and battery lifespan.

Innovation Solution

A binder for rechargeable lithium batteries is developed, comprising a combination of units derived from (meth)acrylic monomers with carboxylic acid groups, amide or nitrile groups, and Zwitterionic vinyl or (meth)acrylic monomers, which enhances adhesive strength and reduces electrical resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a binder is designed to increase adhesive strength of active material layer to current collector, then adhesive strength is improved, but electrical resistance increases

Engineering Contradiction:
Improveadhesive strengthVSAvoidelectrical resistance
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The binder uses a composite polymer structure combining polyacrylic acid (or its metal salt) with polyacrylonitrile (or polyamide) in a specific ratio (30-70 wt% and 70-30 wt% respectively). This composite structure integrates the strong adhesive properties of polyacrylic acid with the conductive characteristics of polyacrylonitrile, achieving both high adhesive strength and low electrical resistance simultaneously

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes the molecular weight parameters of the polymer components (polyacrylic acid: 100,000-1,000,000 g/mol; polyacrylonitrile: 50,000-500,000 g/mol) and their composition ratio to achieve the optimal balance between adhesive strength and electrical conductivity. By controlling these parameters, the binder maintains strong adhesion while minimizing electrical resistance

Inventive Principle:
Principle #35Parameter changes

2Speed

If rapid charging is implemented to improve charging speed, then charging rate is improved, but cell capacity is reduced through reduction in cell lifespan

Engineering Contradiction:
Improvecharging rateVSAvoidcell lifespan
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The optimized binder composition and molecular weight parameters reduce internal resistance of the electrode, enabling faster ion transport and electron conduction. This allows rapid charging at higher C-rates without causing excessive heat generation or mechanical stress that would degrade the cell, thereby maintaining cell lifespan even at improved charging speeds

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The composite binder structure provides both strong adhesion to maintain electrode integrity during rapid charging cycles and sufficient conductivity to handle high current loads. This dual functionality enables rapid charging while preventing the capacity reduction and lifespan degradation typically associated with fast charging

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The binder achieves high adhesive strength of active material layers to current collectors while reducing electrical resistance, leading to improved charging rates and extended battery lifespan.

Implementation Method 1

a unit derived from a (meth)acrylic monomer containing a carboxylic acid group or a carboxylic acid metal salt

Methodology Applied
Scientific EffectCoordinate bonding: Chemical Bonding

Implementation Method 2

a unit derived from a (meth)acrylic monomer containing an amide group or a nitrile group

Methodology Applied
Scientific EffectDipole-dipole interaction:

Implementation Method 3

a unit derived from a (meth)acrylic monomer containing an amide group or a nitrile group

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 4

a unit derived from a Zwitterionic vinyl or (meth)acrylic monomer

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Data Source

PatentUS20250125364A1Binder for rechargeable lithium battery and rechargeable lithium battery including the same
Publication Date: 2025.04.17 SAMSUNG SDI CO LTD
  • US20250125364A1 patent drawing
  • US20250125364A1 patent drawing
  • US20250125364A1 patent drawing

AI summary

A binder for rechargeable lithium batteries and a rechargeable lithium battery including the binder are disclosed. The binder for rechargeable lithium batteries includes a unit derived from a (meth)acrylic monomer containing a carboxylic acid group or a carboxylic acid metal salt as a first monomer; a unit derived from a (meth)acrylic monomer containing an amide group or a nitrile group as a second monomer; and a unit derived from a Zwitterionic vinyl or (meth)acrylic monomer as a third monomer.