Zwitterionic Polymers for Salt-Tolerant Cement Fluid Loss Control

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Solution Overview

Problem

Traditional fluid loss additives in cement slurries are ineffective at high salt concentrations, particularly magnesium salts, leading to premature dehydration and reduced bond strength, which can be exacerbated by increasing additive concentrations that also act as retarders and viscosifiers.

Innovation Solution

The use of zwitterionic polymers as salt-tolerant fluid loss additives, which maintain effectiveness at moderate concentrations even in the presence of high salt concentrations, minimizing adverse effects on cement slurry properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If the concentration of traditional fluid loss additive is increased to counteract salt concentration, then fluid loss control is improved, but cement slurry properties are adversely affected due to retarder and viscosifier effects

Engineering Contradiction:
Improvefluid loss controlVSAvoidcement slurry properties
Core Design Contradiction:
ReliabilityVSEase of operation

Solution Approach 1:

The patent applies parameter changes by transitioning from traditional fluid loss additives to zwitterionic polymers with different chemical properties. The zwitterionic polymers have unique charge characteristics that allow them to maintain fluid loss control effectiveness in high salt environments without exhibiting the harmful retarder and viscosifier effects of traditional additives. This chemical parameter change resolves the contradiction by finding a substance with fundamentally different properties that performs the desired function without the adverse side effects.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional fluid loss additive is used in high salt concentration environments, then fluid loss control is reduced, but increasing additive concentration causes premature dehydration and decreased compressive strength

Engineering Contradiction:
Improvefluid loss control in salt environmentsVSAvoidcompressive strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent resolves this contradiction by changing the chemical parameter of the fluid loss additive from traditional polymers to zwitterionic polymers. The zwitterionic structure provides salt tolerance and maintains fluid loss control in high salt concentrations without causing premature dehydration, thereby preserving compressive strength. The unique charge balance of zwitterionic polymers allows them to function effectively in salt environments without the harmful dehydration effects.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If traditional fluid loss additive concentration is increased to maintain effectiveness, then fluid loss control is improved, but bond strength is negatively impacted

Engineering Contradiction:
Improvefluid loss controlVSAvoidbond strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent applies parameter changes by using zwitterionic polymers with different chemical characteristics that do not interfere with bond strength development. The zwitterionic structure provides fluid loss control without the retarding effects that prevent proper bonding between cement and formation or pipe string. This parameter change allows simultaneous achievement of fluid loss control and bond strength.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS10975286B2Cement slurries with salt-tolerant fluid loss additives and methods relating thereto
Publication Date: 2021.04.13 HALLIBURTON ENERGY SERVICES INC
  • US10975286B2 patent drawing

AI summary

A cement slurry suitable for use in the presence of high salt concentrations may include a base fluid and dry components that include: a cementitious material, a pozzolanic material, a salt additive, and a salt-tolerant fluid loss additive. The salt-tolerant fluid loss additive may be at least one of the following zwitterionic polymers: (1) a copolymer of at least one anionic monomer and at least one cationic monomer, (2) a copolymer of at least one anionic monomer, at least one cationic monomer, and at least one zwitterionic monomer, (3) a homopolymer of a zwitterionic monomer, or (4) a copolymer of at least one zwitterionic monomer.